Morphology of polyamide 6 confined into carbon nanotubes

被引：0
作者：
Piegat, Agnieszka [1 ]
Staniszewski, Zygmunt [1 ]
Poeppel, Artur [2 ]
El Fray, Miroslawa [1 ]
机构：
[1] West Pomeranian Univ Technol Szczecin, Inst Polymer, PL-70311 Szczecin, Poland
[2] Honda R&D Europe Deutschland, D-63073 Offenbach, Germany
来源：
MATERIALS SCIENCE-POLAND | 2015年 / 33卷 / 02期
关键词：
polyamide; 6; carbon nanotubes; in situ polymerization; nanocomposites; ELECTRICAL-CONDUCTIVITY; NANOCOMPOSITES; POLYMERIZATION; SILICA; COMPOSITES;
D O I：
10.1515/msp-2015-0043
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The preparation of polymer nanocomposites filled with carbon nanotubes requires the nanotubes to be uniformly dispersed and compatible with the polymer matrix. In this work we report a preparation method of polyamide 6 (PA 6) based nano-composite containing multi-walled carbon nanotubes (MWCNT) without any additional surface modification and obtained by in situ polymerization, as a simple method for composites production. The process was assisted by ultrasounds prior to synthesis. With such a method, an interesting morphology of polyamide 6 confined into a multi-walled carbon nanotube as well as grafted on a carbon nanotube surface was observed. For comparative purpose, PA 6 nanocomposites were also prepared from commercially available master batch by melt compounding.
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收藏
页码：306 / 311
页数：6
相关论文
共 22 条
[1]   Recent Advances in Clay/Polymer Nanocomposites [J].
Bitinis, N. ;
Hernandez, M. ;
Verdejo, R. ;
Kenny, J. M. ;
Lopez-Manchado, M. A. .
ADVANCED MATERIALS, 2011, 23 (44) :5229-5236
[2]   Processing and assessment of poly(butylene terephthalate) nanocomposites reinforced with oxidized single wall carbon nanotubes [J].
Broza, G ;
Kwiatkowska, M ;
Roslaniec, Z ;
Schulte, K .
POLYMER, 2005, 46 (16) :5860-5867
[3]   Synthesis of poly(butylene terephthalate) nanocomposite by in-situ interlayer polymerization and characterization of its fiber (I) [J].
Chang, JH ;
An, YU ;
Ryu, SC ;
Giannelis, EP .
POLYMER BULLETIN, 2003, 51 (01) :69-75
[4]   Carbon nanotube-polyaniline hybrid materials [J].
Deng, JG ;
Ding, XB ;
Zhang, WC ;
Peng, YX ;
Wang, JH ;
Long, XP ;
Li, P ;
Chan, ASC .
EUROPEAN POLYMER JOURNAL, 2002, 38 (12) :2497-2501
[5]   SILICA-POLYESTER NANOCOMPOSITES PREPARED BY POLYCONDENSATION IN SITU: SYNTHESIS AND MECHANICAL PROPERTIES [J].
El Fray, Miroslawa ;
Rybko, Michal ;
Piegat, Agnieszka .
POLYMER COMPOSITE MATERIALS: FROM MACRO, MICRO TO NANOSCALE, 2012, 714 :277-282
[6]   Current issues in research on structure-property relationships in polymer nanocomposites [J].
Jancar, J. ;
Douglas, J. F. ;
Starr, F. W. ;
Kumar, S. K. ;
Cassagnau, P. ;
Lesser, A. J. ;
Sternstein, S. S. ;
Buehler, M. J. .
POLYMER, 2010, 51 (15) :3321-3343
[7]   Experimental trends in polymer nanocomposites - a review [J].
Jordan, J ;
Jacob, KI ;
Tannenbaum, R ;
Sharaf, MA ;
Jasiuk, I .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 393 (1-2) :1-11
[8]   Novel clay treatment and preparation of poly(ethylene terephthalate)/clay nanocomposite by in-situ polymerization [J].
Kim, SH ;
Park, SH ;
Kim, SC .
POLYMER BULLETIN, 2005, 53 (04) :285-292
[9]   Formation of metallosupramolecular polymers within highly ordered silica mesochannels [J].
Kimura, M ;
Iwashima, Y ;
Ohta, K ;
Hanabusa, K ;
Shirai, H .
MACROMOLECULES, 2005, 38 (12) :5055-5059
[10]   Control of multiwall carbon nanotubes dispersion in polyamide6 matrix: An assessment through electrical conductivity [J].
Kodgire, Pravin V. ;
Bhattacharyya, Arup R. ;
Bose, Suryasarathi ;
Gupta, Nitin ;
Kulkarni, Ajit R. ;
Misra, Ashok .
CHEMICAL PHYSICS LETTERS, 2006, 432 (4-6) :480-485
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