A Novel 3D Silver-triazolate Coordination Polymer with 6.102 Topology: Synthesis, Crystal Structure and Phosphorescence

被引：0

作者：

Wu Dong ^{[1
]}

Xia Bing ^{[1
]}

Yang Fei-Long ^{[1
]}

Weng Lin-Hong ^{[1
]}

Zhou Ya-Ming ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 05期

关键词：

silver; triazole; photoluminescence; coordination polymer; METAL-ORGANIC FRAMEWORK; COMPLEXES; LUMINESCENT; COPPER(I); PHOTOLUMINESCENCE; DINUCLEAR; LIGANDS; LIGHT;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel three-dimensional (3D) silver(I) coordination polymer, namely [Ag-2(dmtrz)(2)](n) (1) (Hdmtrz = 3,5-dimethyl-1H,1,2,4-triazole), was synthesized through diffusion method. 1 was characterized by elemental analysis, FT-IR spectroscopy, thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. 1 crystallizes in the orthorhombic system, space group Iba2 with a = 12.5026(10), b = 7.6026(6), c = 18.8981(17) angstrom, V = 1796.3(3) angstrom(3), Z = 6, M-r = 407.98, D-c = 2.263 g.cm(-3), mu = 3.252 mm(-1), F(000) = 1176, the final R = 0.0304 and wR = 0.0634 for 1310 observed reflections (I > 2 sigma(I)). In the structure of 1, silver(I) centers are triconnected to dmtrz ligands, forming the (3,3)-connected 3D coordination polymer with a 6.10(2) topology. The luminescence property of 1 was also studied in solid state at room temperature.

引用

页码：685 / 689

页数：5

共 25 条

[11] Blue phosphors of dinuclear and mononuclear copper(I) and silver(I) complexes of 3,5-bis(trifluoromethyl)pyrazolate and the related bis(pyrazolyl)borate [J].

Omary, MA ;

Rawashdeh-Omary, MA ;

Diyabalanage, HVK ;

Dias, HVR .

INORGANIC CHEMISTRY, 2003, 42 (26) :8612-8614

[12] SHELXT - Integrated space-group and crystal-structure determination [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2015, 71 :3-8

[13]

Sheldrick G. M., 1996, PROGRAM EMPIRICAL AB

[14]

Sheldrick G.M., 1993, PROGRAM CRYSTAL STRU

[15] The 3[ndσ*(n+1)pσ] Emissions of Linear Silver(I) and Gold(I) Chains with Bridging Phosphine Ligands [J].

Tong, Glenna So Ming ;

Kui, Steven Chi Fai ;

Chao, Hsiu-Yi ;

Zhu, Nianyong ;

Che, Chi-Ming .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (41) :10777-10789

[16] A Direct White-Light-Emitting Metal-Organic Framework with Tunable Yellow-to-White Photoluminescence by Variation of Excitation Light [J].

Wang, Ming-Sheng ;

Guo, Sheng-Ping ;

Li, Yan ;

Cai, Li-Zhen ;

Zou, Jian-Ping ;

Xu, Gang ;

Zhou, Wei-Wei ;

Zheng, Fa-Kun ;

Guo, Guo-Cong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (38) :13572-+

[17] Self-assembly from silver(I) salts and 3,5-dimethyl-4-amino-1,2,4-triazole: syntheses and crystal structures [J].

Wang, Ying ;

Cheng, Peng .

STRUCTURAL CHEMISTRY, 2007, 18 (05) :677-682

[18] Synthesis, crystal structure, and characterization of new tetranuclear Ag(I) complexes with triazole bridges [J].

Wang, Ying ;

Yi, Long ;

Yang, Xing ;

Ding, Bin ;

Cheng, Peng ;

Liao, Dai-Zheng ;

Yan, Shi-Ping .

INORGANIC CHEMISTRY, 2006, 45 (15) :5822-5829

[19] Triplet emission in soluble mercury(II) polyyne polymers [J].

Wong, WY ;

Liu, L ;

Shi, JX .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (34) :4064-4068

[20] Thermally stable helical chain and octanuclear Ag(I) coordination networks with yellow luminescence [J].

Yan, Chunfeng ;

Chen, Lian ;

Feng, Rui ;

Jiang, Feilong ;

Hong, Maochun .

CRYSTENGCOMM, 2009, 11 (11) :2529-2535

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