A Novel 3D Silver-triazolate Coordination Polymer with 6.102 Topology: Synthesis, Crystal Structure and Phosphorescence

被引：0

作者：

Wu Dong ^{[1
]}

Xia Bing ^{[1
]}

Yang Fei-Long ^{[1
]}

Weng Lin-Hong ^{[1
]}

Zhou Ya-Ming ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 05期

关键词：

silver; triazole; photoluminescence; coordination polymer; METAL-ORGANIC FRAMEWORK; COMPLEXES; LUMINESCENT; COPPER(I); PHOTOLUMINESCENCE; DINUCLEAR; LIGANDS; LIGHT;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel three-dimensional (3D) silver(I) coordination polymer, namely [Ag-2(dmtrz)(2)](n) (1) (Hdmtrz = 3,5-dimethyl-1H,1,2,4-triazole), was synthesized through diffusion method. 1 was characterized by elemental analysis, FT-IR spectroscopy, thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. 1 crystallizes in the orthorhombic system, space group Iba2 with a = 12.5026(10), b = 7.6026(6), c = 18.8981(17) angstrom, V = 1796.3(3) angstrom(3), Z = 6, M-r = 407.98, D-c = 2.263 g.cm(-3), mu = 3.252 mm(-1), F(000) = 1176, the final R = 0.0304 and wR = 0.0634 for 1310 observed reflections (I > 2 sigma(I)). In the structure of 1, silver(I) centers are triconnected to dmtrz ligands, forming the (3,3)-connected 3D coordination polymer with a 6.10(2) topology. The luminescence property of 1 was also studied in solid state at room temperature.

引用

页码：685 / 689

页数：5

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