Investigation of AISI 1040 steel corrosion H2S solution containing chloride ions by digital image processing coupled with in electrochemical techniques

被引:44
作者
Zimer, Alexsandro Mendes [1 ]
Rios, Emerson Costa [1 ]
Dias Mendes, Paulo de Carvalho [1 ]
Goncalves, Wesley Nunes [2 ]
Bruno, Odemir Martinez [2 ]
Pereira, Ernesto Chaves [1 ]
Mascaro, Lucia Helena [1 ]
机构
[1] Univ Fed Sao Carlos UFSCar, Dept Chem, LIEC, BR-13565905 Sao Carlos, SP, Brazil
[2] Univ Sao Paulo, IFSC, Depto Fis, BR-13560970 Sao Carlos, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Sulfidation; Steel; Selective oxidation; Intergranular corrosion; Repassivation; PITTING CORROSION; CARBON-STEEL; HYDROGEN-SULFIDE; STAINLESS-STEEL; IRON; BEHAVIOR;
D O I
10.1016/j.corsci.2011.05.064
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper presents a study of AISI 1040 steel corrosion in aqueous electrolyte of acetic acid buffer containing 3.1 and 31 x 10(-3) mol dm(-3) of Na2S in both the presence and absence of 3.5 wt.% NaCl. This investigation of steel corrosion was carried out using potential polarization, and open-circuit and in situ optical microscopy. The morphological analysis and classification of types of surface corrosion damage by digital image processing reveals grain boundary corrosion and shows a non-uniform sulfide film growth, which occurs preferentially over pearlitic grains through successive formation and dissolution of the film. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3193 / 3201
页数:9
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