Compensating defects in Si-doped AlN bulk crystals

被引:22
作者
Irmscher, K. [1 ]
Schulz, T. [1 ]
Albrecht, M. [1 ]
Hartmann, C. [1 ]
Wollweber, J. [1 ]
Fornari, R. [1 ]
机构
[1] Inst Crystal Growth, D-12489 Berlin, Germany
关键词
AlN bulk crystals; Si doping; compensation;
D O I
10.1016/j.physb.2007.08.178
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The rather low n-type conductivity observed in. Si-doped sublimation-grown AlN bulk crystals is explained by the formation of high concentrations of compensating defects. The model is based on the experimental verification of a shallow impurity band formed by Si donors and the presence of acceptor-like electron traps within 1 eV below the conduction band edge. Further it is suggested that the majority of the Si donors is compensated by deep acceptors in the lower half of the band gap. This compensation model is an alternative to the controversially discussed assumption of Si DX center formation. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:323 / 326
页数:4
相关论文
共 12 条
[1]   Controlled n-type doping of AlN:Si films grown on 6H-SiC(0001) by plasma-assisted molecular beam epitaxy -: art. no. 024106 [J].
Ive, T ;
Brandt, O ;
Kostial, H ;
Friedland, KJ ;
Däweritz, L ;
Ploog, KH .
APPLIED PHYSICS LETTERS, 2005, 86 (02) :024106-1
[2]  
MCKEEVER SWS, 1985, THERMOLUMINESCENCE S, P68
[3]   Stability of deep donor and acceptor centers in GaN, AlN, and BN [J].
Park, CH ;
Chadi, DJ .
PHYSICAL REVIEW B, 1997, 55 (19) :12995-13001
[4]   ADMITTANCE SPECTROSCOPY - A POWERFUL CHARACTERIZATION TECHNIQUE FOR SEMICONDUCTOR CRYSTALS - APPLICATION TO ZNTE [J].
PAUTRAT, JL ;
KATIRCIOGLU, B ;
MAGNEA, N ;
BENSAHEL, D ;
PFISTER, JC ;
REVOIL, L .
SOLID-STATE ELECTRONICS, 1980, 23 (11) :1159-1169
[5]   Substitutional carbon in group-III nitrides:: Ab initio description of shallow and deep levels -: art. no. 075209 [J].
Ramos, LE ;
Furthmüller, J ;
Scolfaro, LMR ;
Leite, JR ;
Bechstedt, F .
PHYSICAL REVIEW B, 2002, 66 (07) :752091-752099
[6]   n-type conductivity in sublimation-grown AIN bulk crystals [J].
Schulz, T. ;
Irmscher, K. ;
Albrecht, M. ;
Hartmann, C. ;
Wollweber, J. ;
Fornari, R. .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2007, 1 (04) :147-149
[7]   Theoretical investigation of native defects, impurities, and complexes in aluminum nitride [J].
Stampfl, C ;
Van de Walle, CG .
PHYSICAL REVIEW B, 2002, 65 (15) :1552121-15521210
[8]  
Sze S.M., 2013, SEMICONDUCTOR DEVICE
[9]   An aluminium nitride light-emitting diode with a wavelength of 210 nanometres [J].
Taniyasu, Y ;
Kasu, M ;
Makimoto, T .
NATURE, 2006, 441 (7091) :325-328
[10]   First-principles calculations for defects and impurities: Applications to III-nitrides [J].
Van de Walle, CG ;
Neugebauer, J .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (08) :3851-3879