Metal Ions Tuned Architectures Based on Diphenic Acid and 1,4-Bis(benzimidazol-1-ylmethyl)-benzene: Syntheses, Structures and Properties

被引：4

作者：

Yang Yu-Ting ^{[1
]}

Tu Chang-Zheng ^{[1
]}

Yao Li-Feng ^{[1
]}

Xu Li-Li ^{[1
]}

Wang Jun-Shi ^{[1
]}

Yin Hong-Ju ^{[1
]}

Wang Fan ^{[1
]}

机构：

[1] Qujing Normal Univ, Coll Chem & Environm Sci, Qujing 655011, Yunnan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 34卷 / 11期

关键词：

coordination polymer; crystal structure; diphenic acid; 1,4-bis(benzimidazol-1-ylmethyl)-benzene; fluorescence; ORGANIC COORDINATION POLYMERS; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; COMPLEXES; LIGANDS; CHAIN; DIMENSIONALITY; FLUORESCENCE; FRAMEWORKS; TOPOLOGY;

D O I：

10.11862/CJIC.2018.257

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel complexes, [Cu-2 (bbix) (dpa)(2)(C2H5OH)(2)](n) (1) and {[Cd (bbix)(0.5)(dpa)] center dot 0.5H(2)O}(n) (2) (H(2)dpa = diphenic acid, bbix=1,4-bis(benzimidazol-1-ylmethyl)-benzene), were synthesized and structurally characterized under solvothermal conditions. Both 1 and 2 exhibit two-dimensional (2D) architecture. Complex 1 has 63 wavelike layer consisting of Cu-dpa helical chains in which the Cu(II) ions as 3-connecting nodes. While the layer structure of 2 consists of one-dimensional chains containing alternated 4-membered and 8-membered rings. Furthermore, the solid-state properties of thermal stability for all crystalline materials and the fluorescence property of 2 at room temperature have been investigated.

引用

页码：2049 / 2056

页数：8

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