One-Pot Synthesis of Stable NIR Tetracene Diimides via Double Cross-Coupling

被引：85

作者：

Yue, Wan ^{[1
,2
]}

Gao, Jing ^{[1
,2
]}

Li, Yan ^{[1
]}

Jiang, Wei ^{[1
]}

Di Motta, Simone ^{[3
,4
]}

Negri, Fabrizia ^{[3
,4
]}

Wang, Zhaohui ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China

[3] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[4] UdR Bologna, INSTM, Bologna, Italy

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 45期

基金：

中国国家自然科学基金;

关键词：

THIN-FILM TRANSISTORS; HIGH-ELECTRON-MOBILITY; ORGANIC ELECTRONICS; HIGH-PERFORMANCE; DERIVATIVES; NAPHTHALENE; CORE; AIR; ZIRCONACYCLOPENTADIENES; SEMICONDUCTORS;

D O I：

10.1021/ja207630a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetracene tetracarboxylic diimides have been synthesized based on direct double ring extension of electrondeficient naphthalene diimides involving metallacyclopentadienes. Atomic structure and electronic transitions responsible for their NIR absorption spectra are investigated with quantum-chemical calculations. In light of their unique structure and admirable photophysical and electronic properties, this new molecular skeleton is promising candidate for n-type semiconductors.

引用

收藏

页码：18054 / 18057

页数：4

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