Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites

被引：1
作者：
Li Xiaohong [1 ,2 ]
Zhao Baowei [1 ]
Zhu Kun [1 ]
Hao Xuekui [2 ]
机构：
[1] Lanzhou Jiaotong Univ, Sch Environm & Municipal Engn, Lanzhou 730070, Peoples R China
[2] Lanzhou Polytech Coll, Dept Civil Engn, Lanzhou 730050, Peoples R China
来源：
CHINESE JOURNAL OF CHEMICAL ENGINEERING | 2011年 / 19卷 / 06期
基金：
中国国家自然科学基金;
关键词：
adsorption; zeolite; modification; nitrophenols; adsorption kinetics; AQUEOUS-SOLUTIONS; P-NITROPHENOL; EQUILIBRIUM; DEGRADATION; OXIDATION; KINETICS; PHENOLS; DYES;
D O I：
10.1016/S1004-9541(11)60075-X
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Removal of nitrophenols (NPs) from aqueous solutions through the adsorption process by using cationic beta-cyclodextrin (CCD) modified zeolite (CCDMZ) was investigated. The effects of particle size, contact time, solution pH values and sodium chloride content in the aqueous on adsorption capacity were evaluated through a series of batch experiments. The results showed that CCDMZ had a higher adsorption capacity for removing NPs at a size fraction of 0.45-0.9 mm while adsorption of NPs on CCDMZ reached equilibrium within 60 min. The adsorption process was apparently influenced by pH values and sodium chloride content in aqueous solution. To ascertain the mechanisms of sorption, the experimental data were modeled by using the pseudo-first and pseudo-second order kinetic equations, and the results indicated that the adsorption kinetics of NPs on CCDMZ well-matched with the pseudo-second order rate expression.
引用
收藏
页码：938 / 943
页数：6
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