Gold(I) complexes with amine ligands. 3. Competition between auriophilic and hydrogen bonding interactions in dimeric species

被引：38

作者：

Jones, PG ^{[1
]}

Ahrens, B ^{[1
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 10期

关键词：

D O I：

10.1039/a805587d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gold(I) complexes (pip)(2)Au+Cl- and (Cy2NH)AuCl (pip = piperidine, Cy = cyclohexyl) crystallise as loose dimers; in the ionic species N-H ... Cl- hydrogen bonding is the main secondary interaction, whereas in the neutral complex the N-H ... Cl hydrogen bonding is weaker but is compensated by an auriophilic interaction.

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页码：1041 / 1042

页数：2

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