Preparation and characterisation of C(70)Ph(9)OH; The first fullerene with a single hydroxy group attached to the cage

被引：29
作者：
Birkett, PR
Avent, AG
Darwish, AD
Kroto, HW
Taylor, R
Walton, DRM
机构：
[1] Sch. of Chem. and Molecular Sciences, University of Sussex, Brighton
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 10期
关键词：
D O I：
10.1039/cc9960001231
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The fullerenol C(70)Ph(9)OH is obtained as a minor product from the reaction of C70Cl10 with benzene/FeCl3 and is chiral due to the attachment of a hydroxy group and a phenyl group across the 7,8-bond; this adjacency inhibits free rotation of the 8-phenyl group.
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页码：1231 / 1232
页数：2
相关论文
共 5 条
[1]   THE STRUCTURE OF C60PH5CL AND C60PH5H, FORMED VIA ELECTROPHILIC AROMATIC-SUBSTITUTION [J].
AVENT, AG ;
BIRKETT, PR ;
CRANE, JD ;
DARWISH, AD ;
LANGLEY, GJ ;
KROTO, HW ;
TAYLOR, R ;
WALTON, DRM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (12) :1463-1464
[2]   HOLEY FULLERENES - A BIS-LACTONE DERIVATIVE OF [70]FULLERENE WITH AN 11-ATOM ORIFICE [J].
BIRKETT, PR ;
AVENT, AG ;
DARWISH, AD ;
KROTO, HW ;
TAYLOR, R ;
WALTON, DRM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (18) :1869-1870
[3]   FORMATION AND CHARACTERIZATION OF C70CL10 [J].
BIRKETT, PR ;
AVENT, AG ;
DARWISH, AD ;
KROTO, HW ;
TAYLOR, R ;
WALTON, DRM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) :683-684
[4]  
BIRKETT PR, 1996, TETRAHEDRON, V52, P5235
[5]  
CHIANG LY, 1995, CHEM FULLERENES, pCH5
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