Cooperative Assembly of Three-Ring-Based Zeolite-Type Metal-Organic Frameworks and Johnson-Type Dodecahedra

被引:126
作者
Zheng, Shou-Tian [1 ]
Zuo, Fan [2 ]
Wu, Tao [2 ]
Irfanoglu, Burcin [1 ]
Chou, Chengtsung [1 ]
Nieto, Ruben A. [1 ]
Feng, Pingyun [2 ]
Bu, Xianhui [1 ]
机构
[1] Calif State Univ Long Beach, Dept Chem & Biochem, 1250 Bellflower Blvd, Long Beach, CA 90840 USA
[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
基金
美国国家科学基金会;
关键词
mixed ligands; organic-inorganic hybrid composites; water splitting; zeolites; LARGE-PORE ZEOLITE; IMIDAZOLATE FRAMEWORKS; BUILDING UNITS; POLYHEDRA; TOPOLOGIES; ZMOFS; FUNCTIONALITY; STABILITY; CHEMISTRY; POLYMERS;
D O I
10.1002/anie.201006882
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two birds with one stone: Cooperative assembly of four-connected indium nodes with two symmetry-complementary ligands leads to both three-ring-based zeolite-type metal-organic frameworks (NPO-type) and the Johnson-type metal-organic polyhedra shown in the picture (grayC, greenIn, blueN, redO). The NPO-zeolite compounds behave as semiconductors and exhibit photocatalytic activity for the generation of dihydrogen from water under ultraviolet irradiation. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1849 / 1852
页数:4
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