Cooperative Assembly of Three-Ring-Based Zeolite-Type Metal-Organic Frameworks and Johnson-Type Dodecahedra

被引：126

作者：

Zheng, Shou-Tian ^{[1
]}

Zuo, Fan ^{[2
]}

Wu, Tao ^{[2
]}

Irfanoglu, Burcin ^{[1
]}

Chou, Chengtsung ^{[1
]}

Nieto, Ruben A. ^{[1
]}

Feng, Pingyun ^{[2
]}

Bu, Xianhui ^{[1
]}

机构：

[1] Calif State Univ Long Beach, Dept Chem & Biochem, 1250 Bellflower Blvd, Long Beach, CA 90840 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 08期

基金：

美国国家科学基金会;

关键词：

mixed ligands; organic-inorganic hybrid composites; water splitting; zeolites; LARGE-PORE ZEOLITE; IMIDAZOLATE FRAMEWORKS; BUILDING UNITS; POLYHEDRA; TOPOLOGIES; ZMOFS; FUNCTIONALITY; STABILITY; CHEMISTRY; POLYMERS;

D O I：

10.1002/anie.201006882

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two birds with one stone: Cooperative assembly of four-connected indium nodes with two symmetry-complementary ligands leads to both three-ring-based zeolite-type metal-organic frameworks (NPO-type) and the Johnson-type metal-organic polyhedra shown in the picture (grayC, greenIn, blueN, redO). The NPO-zeolite compounds behave as semiconductors and exhibit photocatalytic activity for the generation of dihydrogen from water under ultraviolet irradiation. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1849 / 1852

页数：4

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