Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption

被引：94

作者：

Li, Zi-Jian ^{[1
]}

Ju, Yu ^{[1
,2
]}

Yu, Bowen ^{[1
]}

Wu, Xiaoling ^{[1
]}

Lu, Huangjie ^{[1
]}

Li, Yongxin ^{[3
]}

Zhou, Jing ^{[1
]}

Guo, Xiaofeng ^{[4
,5
]}

Zhang, Zhi-Hui ^{[2
]}

Lin, Jian ^{[1
]}

Wang, Jian-Qiang ^{[1
,6
]}

Wang, Shuao ^{[7
,8
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, 2019 Jia Luo Rd, Shanghai 201800, Peoples R China

[2] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

[4] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[5] Washington State Univ, Alexandra Navrotsky Inst Expt Thermodynam, Pullman, WA 99164 USA

[6] Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

[7] Soochow Univ, State Key Lab Radiat Med & Protect, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China

[8] Soochow Univ, Collaborat Innovat Ctr Radiol Med Jiangsu Higher, Suzhou 215123, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 49期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; CAPTURE; DESIGN;

D O I：

10.1039/d0cc02841j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Modulated synthesis and isoreticular expansion of Th-MOFs enable the stepwise construction of hierarchical complexes in which porosity and functionality can be fine-tuned, affording new Th-MOFs with a record high void space (74.0%), the largest surface area (3396.5 m(2)g(-1)) among thorium materials, and excellent adsorption capacities toward radioactive iodine.

引用

页码：6715 / 6718

页数：4

共 9 条

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