Three-Dimensional Printing with Biomass-Derived PEF for Carbon-Neutral Manufacturing

被引：108

作者：

Kucherov, Fedor A. ^{[1
]}

Gordeev, Evgeny G. ^{[1
]}

Kashin, Alexey S. ^{[1
]}

Ananikov, Valentine P. ^{[1
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Leninsky Prospekt 47, Moscow 119991, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 50期

基金：

俄罗斯科学基金会;

关键词：

biomass; carbon-neutral cycle; polymer chemistry; sustainable chemistry; three-dimensional printing; RENEWABLE RESOURCES; POLYMERS; FUTURE; POLY(ETHYLENE-TEREPHTHALATE); CONVERSION; FUELS;

D O I：

10.1002/anie.201708528

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biomass-derived poly(ethylene-2,5-furandicarboxylate) (PEF) has been used for fused deposition modeling (FDM) 3D printing. A complete cycle from cellulose to the printed object has been performed. The printed PEF objects created in the present study show higher chemical resistance than objects printed with commonly available materials (acrylonitrile butadiene styrene (ABS), polylactic acid (PLA), glycol-modified poly(ethylene terephthalate) (PETG)). The studied PEF polymer has shown key advantages for 3D printing: optimal adhesion, thermoplasticity, lack of delamination and low heat shrinkage. The high thermal stability of PEF and relatively low temperature that is necessary for extrusion are optimal for recycling printed objects and minimizing waste. Several successive cycles of 3D printing and recycling were successfully shown. The suggested approach for extending additive manufacturing to carbon-neutral materials opens a new direction in the field of sustainable development.

引用

页码：15931 / 15935

页数：5

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