Photopolymerization kinetics of multifunctional monomers

被引：827
作者：
Andrzejewska, E [1 ]
机构：
[1] Poznan Univ Technol, Fac Chem Technol, PL-60965 Poznan, Poland
来源：
PROGRESS IN POLYMER SCIENCE | 2001年 / 26卷 / 04期
关键词：
photopolymerization; kinetics; linear systems; crosslinking systems; modeling; propagation and termination rate coefficients; termination mechanism; effect of monomer structure and system composition; effect of temperature; effect of heteroatoms;
D O I：
10.1016/S0079-6700(01)00004-1
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This review article presents results of investigations concerning the kinetics of crosslinking photopolymerizations. The main emphasis is given to the propagation and termination rate coefficients and to the determination of the mechanism of the termination process. To emphasize the special features of the kinetics of the photocrosslinking process, a comparison with the kinetics of linear polymerizations has been made. Moreover, the paper describes the influence of various factors, both chemical as well as physical (e.g. monomer, structure, system composition, oxygen, temperature) on the chemistry of network formation. The effects of amino, ether and sulfide groups present in additives or introduced within monomer molecules are also discussed. (C) 2001 Elsevier Science Ltd. AU rights reserved.
引用
收藏
页码：605 / 665
页数：61
相关论文
共 223 条
[21]  
ANDRZEJEWSKA E, 1997, 8 C RAD CUR RADT EUR, P151
[22]  
ANDRZEJEWSKA E, 1994, POLIMERY WARSAW, V39, P22
[23]  
ANDRZEJEWSKA E, IN PRESS MACROMOL S
[24]  
ANDRZEWSKA E, 2000, WORLD POL C IUPAC MA, P237
[25]   KINETIC GELATION PREDICTIONS OF SPECIES AGGREGATION IN TETRAFUNCTIONAL MONOMER POLYMERIZATIONS [J].
ANSETH, KS ;
BOWMAN, CN .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1995, 33 (12) :1769-1780
[26]   KINETIC EVIDENCE OF REACTION-DIFFUSION DURING THE POLYMERIZATION OF MULTI(METH)ACRYLATE MONOMERS [J].
ANSETH, KS ;
WANG, CM ;
BOWMAN, CN .
MACROMOLECULES, 1994, 27 (03) :650-655
[27]   Radical concentrations, environments, and reactivities during crosslinking polymerizations [J].
Anseth, KS ;
Anderson, KJ ;
Bowman, CN .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (03) :833-848
[28]   REACTION-KINETICS AND VOLUME RELAXATION DURING POLYMERIZATIONS OF MULTIETHYLENE GLYCOL DIMETHACRYLATES [J].
ANSETH, KS ;
KLINE, LM ;
WALKER, TA ;
ANDERSON, KJ ;
BOWMAN, CN .
MACROMOLECULES, 1995, 28 (07) :2491-2499
[29]   POLYMERIZATION KINETICS AND VOLUME RELAXATION BEHAVIOR OF PHOTOPOLYMERIZED MULTIFUNCTIONAL MONOMERS PRODUCING HIGHLY CROSS-LINKED NETWORKS [J].
ANSETH, KS ;
BOWMAN, CN ;
PEPPAS, NA .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (01) :139-147
[30]   REACTION BEHAVIOR AND KINETIC CONSTANTS FOR PHOTOPOLYMERIZATIONS OF MULTI(METH)ACRYLATE MONOMERS [J].
ANSETH, KS ;
WANG, CM ;
BOWMAN, CN .
POLYMER, 1994, 35 (15) :3243-3250
12345678910