Photopolymerization kinetics of multifunctional monomers

被引：824
作者：
Andrzejewska, E [1 ]
机构：
[1] Poznan Univ Technol, Fac Chem Technol, PL-60965 Poznan, Poland
来源：
PROGRESS IN POLYMER SCIENCE | 2001年 / 26卷 / 04期
关键词：
photopolymerization; kinetics; linear systems; crosslinking systems; modeling; propagation and termination rate coefficients; termination mechanism; effect of monomer structure and system composition; effect of temperature; effect of heteroatoms;
D O I：
10.1016/S0079-6700(01)00004-1
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This review article presents results of investigations concerning the kinetics of crosslinking photopolymerizations. The main emphasis is given to the propagation and termination rate coefficients and to the determination of the mechanism of the termination process. To emphasize the special features of the kinetics of the photocrosslinking process, a comparison with the kinetics of linear polymerizations has been made. Moreover, the paper describes the influence of various factors, both chemical as well as physical (e.g. monomer, structure, system composition, oxygen, temperature) on the chemistry of network formation. The effects of amino, ether and sulfide groups present in additives or introduced within monomer molecules are also discussed. (C) 2001 Elsevier Science Ltd. AU rights reserved.
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页码：605 / 665
页数：61
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