Iodine/aqueous NH4OAc:: an improved reaction system for direct oxidative conversion of aldehydes and alcohols into nitriles

被引：9

作者：

Ren, Yi-Ming ^{[1
]}

Zhu, Yi-Zhong ^{[1
]}

Cai, Chun ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2008年 / 01期

关键词：

molecular iodine; cyanation; aldehydes; primary alcohols; oxidation; ammonium acetate;

D O I：

10.3184/030823408X283711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient method for direct oxidative conversion of aldehydes and alcohols into nitriles has been developed by using the inexpensive and environmentally friendly reagent I-2/aqueous NH4OAc. The aqueous NH4OAc as a nontoxic cyanide source is more eco-friendly than aqueous ammonia, because gaseous ammonia evaporates easily from aqueous ammonia but not from aqueous NH4OAc.

引用

页码：18 / 19

页数：2

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