Nano oxalates of Fe, Co, Ni: Burning rate modifiers for composite solid propellants

被引：40

作者：

Singh, Supriya ^{[1
]}

Srivastava, Pratibha ^{[1
]}

Singh, Gurdip ^{[1
]}

机构：

[1] DDU Gorakhpur Univ, Dept Chem, Gorakhpur 273009, Uttar Pradesh, India

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2015年 / 27卷

关键词：

Nanostructures; Electron microscopy; Differential scanning calorimetry; Adsorption; X-RAY CRYSTALLOGRAPHY; THERMAL-DECOMPOSITION; AMMONIUM-PERCHLORATE; ENERGETIC COMPOUNDS; RATE CATALYSTS; THERMOLYSIS; COPPER; COMBUSTION; COMPLEXES; IGNITION;

D O I：

10.1016/j.jiec.2014.11.047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We highlight here current research focused on the catalytic activity of nano oxalates of Fe, Co and Ni synthesized by colloidal precipitation method. The catalytic activity of these nano oxalates was examined for the thermal decomposition of ammonium perchlorate (AP) and composite solid propellants (CSPs) using thermogravimetry (TG), TG coupled with differential scanning calorimetry (TG-DSC) and ignition delay measurements. All the nano oxalates showed very high activity as burning rate catalysts for composite solid propellants (CSPs) containing hydroxyl terminated polybutadiene (HTPB) as binder and AP as oxidizer. CoC2O4 center dot 2H(2)O was found to be the best catalyst in terms of lowering decomposition temperature of both AP and CSPs. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：88 / 95

页数：8

共 43 条

[1] ESTIMATION OF AMMONIUM-PERCHLORATE IN HTPB BASED COMPOSITE SOLID-PROPELLANTS USING KJELDAHL METHOD [J].

AJAZ, AG .

JOURNAL OF HAZARDOUS MATERIALS, 1995, 42 (03) :303-306

[2] Correlation between the morphology of cobalt oxalate precursors and the microstructure of metal cobalt powders and compacts [J].

Baco-Carles, V. ;

Arnal, A. ;

Poquillon, D. ;

Tailhades, Ph. .

POWDER TECHNOLOGY, 2008, 185 (03) :231-238

[3] PARTICLE SIZE DETERMINATION FROM X-RAY LINE BROADENING [J].

BIRKS, LS ;

FRIEDMAN, H .

JOURNAL OF APPLIED PHYSICS, 1946, 17 (08) :687-691

[4] Thermal decomposition of ammonium perchlorate [J].

Boldyrev, VV .

THERMOCHIMICA ACTA, 2006, 443 (01) :1-36

[5]

Brown M.E., 1997, COMPREHENSIVE CHEM K, V22, P1

[6]

DAUERMAN L, 1967, AIAA J, V5, P192, DOI 10.2514/3.3941

[7] THERMAL DECOMPOSITION OF AMMONIUM PERCHLORATE [J].

DAVIES, JV ;

JACOBS, PWM ;

RUSSELLJ.A .

TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (535P) :1737-&

[8] Bi-metallic nanocomposites of Mn with very high catalytic activity for burning rate enhancement of composite solid propellants [J].

Dubey, Reena ;

Chawla, Mohit ;

Siril, Prem Felix ;

Singh, Gurdip .

THERMOCHIMICA ACTA, 2013, 572 :30-38

[9] THE APPLICATION OF THE ABSOLUTE RATE THEORY TO THE IGNITION OF PROPAGATIVELY REACTING SYSTEMS - THE THERMAL IGNITION OF THE SYSTEMS LITHIUM NITRATE-MAGNESIUM, SODIUM NITRATE-MAGNESIUM [J].

FREEMAN, ES ;

GORDON, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1956, 60 (07) :867-871

[10] IGNITION OF COMPOSITE SOLID-PROPELLANTS BY HOT PLATE TECHNIQUE [J].

GIRDHAR, HL ;

ARORA, AJ .

COMBUSTION AND FLAME, 1978, 31 (03) :245-250

← 1 2 3 4 5 →