Direct detection of multiple pesticides in honey by neutral desorption-extractive electrospray ionization mass spectrometry

被引：23
作者：
Deng, Min [1 ]
Yu, Tenghui [1 ]
Luo, Huolin [1 ]
Zhu, Tenggao [2 ]
Huang, Xueyong [1 ]
Luo, Liping [1 ,3 ]
机构：
[1] Nanchang Univ, Sch Life Sci, Nanchang 330031, Jiangxi, Peoples R China
[2] East China Univ Technol, Jiangxi Key Lab Mass Spectrometry & Instrumentat, Nanchang 330013, Jiangxi, Peoples R China
[3] Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330031, Jiangxi, Peoples R China
来源：
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2017年 / 422卷
基金：
中国国家自然科学基金;
关键词：
Neutral desorption-extractive electrospray ionization; Mass spectrometry; Multiple pesticides; Honey; Direct analysis; LIQUID-LIQUID MICROEXTRACTION; GAS-CHROMATOGRAPHY; LC-MS/MS; RESIDUES; WATER; TRAP; ORGANOCHLORINE; INSECTICIDES; APIARIES; SORBENT;
D O I：
10.1016/j.ijms.2017.09.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
An analytical method was developed and validated for the simultaneous determination of residues of three kinds of organophosphorus insecticides and two kinds of carbamate insecticides in honey using neutral desorption-extractive electrospray ionization mass spectrometry (ND-EESI-MS) without any sample pretreatment. The detection limits of the assay ranged from 1.16 to 4.18 ng/g or the studied pesticides. The developed assay was linear over the concentration range of 20.00-1000.00 ng/mL, with correlation coefficients of more than 0.996, and the recoveries ranged between 87.00% and 114.98%, with RSD lower than 6.22% for all pesticides. The matrix effect for all of the pesticides showed signal suppression except for chlorpyrifos-methyl. This ND-EESI-MS method was proved to be effective for the detection of pesticide residues by analyzing eighteen kinds of commercial honey in this study. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：111 / 118
页数：8
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