Alkyl formates as reagents for reductive amination of carbonyl compounds

被引：7

作者：

Afanasyev, Oleg I. ^{[1
]}

Cherkashehenko, Ilia ^{[2
]}

Kuznetsov, Anton ^{[3
]}

Kliuev, Fedor ^{[3
]}

Semenov, Sergey ^{[3
]}

Chusova, Olga ^{[4
]}

Denisova, Gleb ^{[1
]}

Chusov, Denis ^{[1
,5
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[3] VI Chuikov Moscow South Eastern Sch, Moscow 109457, Russia

[4] RUDN Univ, Peoples Friendship Univ Russia, Moscow 117198, Russia

[5] GV Plekhanov Russian Univ Econ, Moscow 117997, Russia

来源：

MENDELEEV COMMUNICATIONS | 2020年 / 30卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

reduction; reductive amination; formic acid esters; carbon monoxide surrogates; rhodium; EX-SITU GENERATION; ARYL FORMATES; ALDEHYDES; MONOXIDE; HYDROESTERIFICATION; COMPLEXES; HALIDES; KETONES; RHODIUM; CO;

D O I：

10.1016/j.mencom.2020.01.037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl formates in the presence of basic additives can serve as a reagent in the direct reductive amination of carbonyl compounds. The developed procedure can be applied to various aldehydes and ketones with electron donating and electron withdrawing groups.

引用

页码：112 / 113

页数：2

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