TDI-IPDI Waterborne polyurethane emulsions: properties and application

被引：0

作者：

Guo, Yuhua ^{[1
]}

Li, Shucai ^{[1
]}

Wang, Gaosheng ^{[1
]}

机构：

[1] Tianjin Univ Sci & Technol, Coll Mat Sci & Chem Engn, Tianjin 300222, Peoples R China

来源：

FUNDAMENTAL OF CHEMICAL ENGINEERING, PTS 1-3 | 2011年 / 233-235卷

关键词：

Waterborne polyurethane emulsions (WPUs); surface sizing; Cobb; Tolylene isocyanate (TDI); Isophorone diisocyanate (IPDI); CROSS-LINKING;

D O I：

10.4028/www.scientific.net/AMR.233-235.1700

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

TDI as main isocyanate, IPDI as end-capping reagent, waterborne polyurethane emulsions (WPUs) surface-sizing agent have been obtained. The properties of WPUs and papers sized by WPUs with different DMPA content, different NCO/OH molar ratio and nNCO(TDI)/nNCO(IPDI) are systematically examined. The results show that WPUs are new kinds of surface sizing agents with good properties. The water resistance, surface gloss and smoothness of papers sized by WPUs have dramatically increased. The folding endurance, tearing resistance and tensile strength of WPU sized papers are observed to increase obviously.

引用

页码：1700 / 1703

页数：4

共 9 条

[1] 2K waterborne clearcoat -: a competition between crosslinking and side reactions [J].

Collong, W ;

Göbel, A ;

Kleuser, B ;

Lenhard, W ;

Sonntag, M .

PROGRESS IN ORGANIC COATINGS, 2002, 45 (2-3) :205-209

[2] Chain extension study of aqueous polyurethane dispersions [J].

Jhon, YK ;

Cheong, IW ;

Kim, JH .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2001, 179 (01) :71-78

[3] Cross-linking reaction of waterborne polyurethane adhesives containing different amount of ionic groups with hexamethoxymethyl melamine [J].

Rahman, Mohammad Mizanur ;

Kim, Eun-Young ;

Kwon, Ji Yun ;

Yoo, Hye-Jin ;

Kim, Han-Do .

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2008, 28 (1-2) :47-54

[4]

VOLKER D, 1998, PROG ORG COAT, V34, P200

[5] Mixture design approaches to IPDI-H6XDI-XDI ternary diisocyanate-based waterborne polyurethanes [J].

Yang, CH ;

Yang, HJ ;

Wen, TC ;

Wu, MS ;

Chang, JS .

POLYMER, 1999, 40 (04) :871-885

[6] Preparation and properties of amino-terminated anionic waterborne-polyurethane-silica hybrid materials through a sol-gel process in the absence of an external catalyst [J].

Yeh, Jui-Ming ;

Yao, Chia-Tseng ;

Hsieh, Chi-Fa ;

Yang, Hsing-Chung ;

Wu, Chi-Phi .

EUROPEAN POLYMER JOURNAL, 2008, 44 (09) :2777-2783

[7] The solution properties and membrane properties of polydimethylsiloxane waterborne polyurethane blended with the waterborne polyurethanes of various kinds of soft segments [J].

Yen, Meng-Shung ;

Tsai, Ping-Yuan ;

Hong, Po-Da .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 279 (1-3) :1-9

[8] Effects of solid substrate on structure and properties of casting waterborne polyurethane/carboxymethylchitin films [J].

Zeng, M ;

Zhang, LN ;

Zhou, YX .

POLYMER, 2004, 45 (10) :3535-3545

[9] Synthesis and characterization of a new compound bearing ketone and hydroxyl groups for preparation of ambient temperature self-crosslinking waterborne polyurethanes [J].

Zhu, Xiaoli ;

Zhang, Qingsi ;

Liu, Leili ;

Kong, Xiang Z. ;

Feng, Shengyu .

PROGRESS IN ORGANIC COATINGS, 2007, 59 (04) :324-330

← 1 →