Study on the phase separation of La0.7Sr0.3MnO3 nanoparticles by electron magnetic resonance

被引:3
作者
Wu, J. H. [1 ]
Lin, J. G. [1 ,2 ]
机构
[1] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 106, Taiwan
[2] Natl Taiwan Univ, Ctr Nanostorage Res, Taipei 106, Taiwan
关键词
La0.7Sr0.3MnO3; nanoparticles; CMR; Phase separation; Electron magnetic resonance;
D O I
10.1016/j.jmmm.2006.02.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, the technique of electron magnetic resonance (EMR) is used to measure the magnetic resonant spectra of La0.7Sr0.3MnO3 nanoparticles synthesized by sol-gel routes with three different gelation agents (S1: Urea + citric acid; S2: citric acid, and S3: Urea + trisodium citrate). The purpose of this study is to investigate the influence of synthesis conditions on the magnetic properties of nanoparticles. Our ESR results show that Curie temperatures of La0.7Sr0.3MnO3 nanoparticles with different gelation agents are slightly different (T-c similar to 340 to 360 K) and possess both paramagnetic (PM) and ferromagnetic (FM) phases in the temperature below T-c. Besides, a sharp FM-PM transition indicates that the combined agent of Urea + tri-sodium citrate creates a better quality in CMR nanomagnets. (C) 2006 Elsevier B. V. All rights reserved.
引用
收藏
页码:E7 / E9
页数:3
相关论文
共 5 条
[1]   Spatially inhomogeneous metal-insulator transition in doped manganites [J].
Fäth, M ;
Freisem, S ;
Menovsky, AA ;
Tomioka, Y ;
Aarts, J ;
Mydosh, JA .
SCIENCE, 1999, 285 (5433) :1540-1542
[2]   Large magnetotunneling effect at low magnetic fields in micrometer-scale epitaxial La0.67Sr.033MnO3 tunnel junctions [J].
Lu, Y ;
Li, XW ;
Gong, GQ ;
Xiao, G ;
Gupta, A ;
Lecoeur, P ;
Sun, JZ ;
Wang, YY ;
Dravid, VP .
PHYSICAL REVIEW B, 1996, 54 (12) :R8357-R8360
[3]   Observation of magnetic inhomogeneities in crystalline-doped manganites by electron magnetic resonance [J].
Shames, AI ;
Rozenberg, E ;
McCarroll, WH ;
Greenblatt, M ;
Gorodetsky, G .
PHYSICAL REVIEW B, 2001, 64 (17)
[4]   Temperature dependent, non-ohmic magnetoresistance in doped perovskite manganate trilayer junctions [J].
Sun, JZ ;
KrusinElbaum, L ;
Duncombe, PR ;
Gupta, A ;
Laibowitz, RB .
APPLIED PHYSICS LETTERS, 1997, 70 (13) :1769-1771
[5]   Magnetoresistive La0.83Sr0.17MnO3 ceramics by DAAS technique [J].
Yang, S ;
Lin, CT ;
Rogacki, K ;
Dabrowski, B ;
Adams, PM ;
Speckman, DM .
CHEMISTRY OF MATERIALS, 1998, 10 (05) :1374-1381