In research of the low temperature parts of atmospheric pressure device, by using BP neural network, the connection of PH value, Cl-, H2S and Fe+2 was setup which can predict Fe+2 content accurately, and obtain the requirement accuracy, hence more accurate corrosion can be predicted and providing more suggests for corrosion protection. This paragraph includes the DUSHANZI petrochemical atmospheric pressure equipment files, pipeline and the archives of each equipment material content data, and then analysis the corrosion situation, concludes the corrosion types mainly about(I)Low temperature HCl-H2S-H2O corrosion. (2) High temperature naphthenic acid corrosion. (3) High temperature S and H2S corrosion. Among them, the corrosion of the low temperature parts of atmospheric pressure device is seriously affected the safety of the oil production, also it is the main corrosion of atmospheric device. The low temperature parts of DUSHANZI petrochemical atmospheric pressure device will be a training sample of neural network, to build a corrosion prediction model.