Analysis of pyrolysis products formed from ethylene-tetrafluoroethylene heterosequences of poly(ethylene-co-tetrafluoroethylene)

Poly(ethylene-co-tetrafluoroethylene) (PETFE) was pyrolyzed and the pyrolysis products formed from the ethylene-tetrafluoroethylene heterosequences were analyzed using gas chromatography/mass spectrometry (GC/MS). Major pyrolysis products were 3,3-difluoropropene (DFP), 3,3,4,4-tetrafluoro-1-butene (TFB), 1,1,2,2,3,3-hexafluorocyclopentane (HFCP), 1,1,2,2,3,3-hexafluorocyclohexane (HFCH), 1,1,2,2,3,3,4,4-octafluorocyclohexane (OFCH), and 3-trifluoromethyl-3,4,4,5,5-pentafluorocyclohexene (FMPFCH). Their formation mechanisms were proposed. Peak intensity ratios of HFCP, HFCH, and FMPFCH compared to OFCH increased as the pyrolysis temperature increased, while those of DEP, TFB, HFCP, and HFCH compared to tetrafluoroethylene decreased. Order of the relative abundances of the major pyrolysis products formed from PETFE was OFCH > HFCP > HFCH > TFB > DEP. The order may be due to the difference in bond energies of CH2-CH2. CF2-CH2, and CF2-CF2. Formation of the pyrolysis product through the CH2-CH2 bond cleavage was more favorable than those through the CF2-CH2 and CF2-CF2 ones. (C) 2011 Elsevier B.V. All rights reserved.