Syntheses, characterizations and SOD-like activities of ternary copper(II) complexes with 1,10-phenanthroline and L-α-amino acids

被引：16

作者：

Liao, Sheng Rong ^{[1
]}

Le, Xue Yi ^{[1
]}

Feng, Xiao Long ^{[2
]}

机构：

[1] S China Agr Univ, Coll Sci, Dept Appl Chem, Guangzhou 510642, Peoples R China

[2] Sun Yat Sen Univ, Ctr Anal & Measurement, Guangzhou 510275, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 06期

关键词：

copper(II) complexes; superoxide dismutase (SOD); SOD-like activity; L-alpha-amino acids;

D O I：

10.1080/00958970701476943

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new complexes, [Cu(phen)(L-argH+)Cl]Cl . 2.5H(2)O (1), [Cu(phen)(L-leu)(H2O)]Cl . 2.5H(2)O (2) and [Cu(phen)(L-met)(H2O)]Cl . 2H(2)O (3), where phen = 1,10-phenanthroline, L-arg = L-argininate, L-leu = L-leucinate, and L-met = L-methioninate, were synthesized and characterized by elemental analysis, molar conductivity, IR and UV-Vis spectroscopies. Complex 1 was structurally characterized by single-crystal X-ray diffraction. The superoxide dismutase (SOD)-like activities of the three complexes were determined by the improved NBT method. The results show that the complexes have high superoxide dismutase-like activities and may act as good mimics for superoxide dismutases.

引用

页码：847 / 856

页数：10