A mild and efficient oxidation of alcohols to ketones with lodosobenzene/(salen) manganese complex

被引：5
作者：
Kim, SS [1 ]
Borisova, G
机构：
[1] Inha Univ, Dept Chem, Inchon 402751, South Korea
[2] Inha Univ, Ctr Chem Dynam, Inchon 402751, South Korea
来源：
SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 22期
关键词：
alcohol; ketone; chemoselective; Mn(salen); iodosobenzene;
D O I：
10.1081/SCC-120026321
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An excellent method for the chemoselective oxidation of alcohols to ketones with C6H5IO catalyzed by (salen) manganese/4 Angstrom MS in CH3CN has been devised. The reported procedure is fast, simple, and the yields are excellent ( > 95%) in most cases.
引用
收藏
页码：3961 / 3967
页数：7
相关论文
共 20 条
[1]   Chemoselective C-H oxidation of alcohols to carbonyl compounds with iodosobenzene catalyzed by (salen)chromium complex [J].
Adam, W ;
Gelalcha, FG ;
Saha-Möller, CR ;
Stegmann, VR .
JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (07) :1915-1918
[2]   A highly chemoselective oxidation of alcohols to carbonyl products with iodosobenzene diacetate mediated by chromium(III)(salen) complexes:: Synthetic and mechanistic aspects [J].
Adam, W ;
Hajra, S ;
Herderich, M ;
Saha-Möller, CR .
ORGANIC LETTERS, 2000, 2 (18) :2773-2776
[3]   HIGHLY ENANTIOSELECTIVE, CATALYTIC EPOXIDATION OF TRISUBSTITUTED OLEFINS [J].
BRANDES, BD ;
JACOBSEN, EN .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (16) :4378-4380
[4]   EFFECT OF CHIRAL QUATERNARY AMMONIUM-SALTS ON (SALEN)MN-CATALYZED EPOXIDATION OF CIS-OLEFINS - A HIGHLY ENANTIOSELECTIVE, CATALYTIC ROUTE TO TRANS-EPOXIDES [J].
CHANG, SB ;
GALVIN, JM ;
JACOBSEN, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) :6937-6938
[5]  
HAMADA T, 1994, SYNLETT, P479
[6]   CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS [J].
IRIE, R ;
NODA, K ;
ITO, Y ;
MATSUMOTO, N ;
KATSUKI, T .
TETRAHEDRON LETTERS, 1990, 31 (50) :7345-7348
[7]  
IRIE R, 1991, SYNLETT, P265
[8]   HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYSTS DERIVED FROM 1,2-DIAMINOCYCLOHEXANE [J].
JACOBSEN, EN ;
ZHANG, W ;
MUCI, AR ;
ECKER, JR ;
DENG, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7063-7064
[9]  
Larock R.C., 1989, COMPREHENSIVE ORGANI
[10]   A PRACTICAL METHOD FOR THE LARGE-SCALE PREPARATION OF [N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)1,2-CYCLOHEXANEDIAMINATO(2-)]MANGANESE(III) CHLORIDE, A HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYST [J].
LARROW, JF ;
JACOBSEN, EN ;
GAO, Y ;
HONG, YP ;
NIE, XY ;
ZEPP, CM .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (07) :1939-1942
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