Dynamics of nanoparticles in a supercooled liquid

被引:123
作者
Caronna, Chiara [1 ,2 ]
Chushkin, Yuriy [1 ]
Madsen, Anders [1 ]
Cupane, Antonio [2 ]
机构
[1] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[2] Dept Phys & Astron Sci, I-90123 Palermo, Italy
关键词
D O I
10.1103/PhysRevLett.100.055702
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The dynamic properties of nanoparticles suspended in a supercooled glass forming liquid are studied by x-ray photon correlation spectroscopy. While at high temperatures the particles undergo Brownian motion the measurements closer to the glass transition indicate hyperdiffusive behavior. In this state the dynamics is independent of the local structural arrangement of nanoparticles, suggesting a cooperative behavior governed by the near-vitreous solvent.
引用
收藏
页数:4
相关论文
共 26 条
[1]   PERSPECTIVE ON THE GLASS-TRANSITION [J].
ANGELL, CA .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1988, 49 (08) :863-871
[2]   Aging processes and scale dependence in soft glassy colloidal suspensions [J].
Bellour, M ;
Knaebel, A ;
Harden, JL ;
Lequeux, F ;
Munch, JP .
PHYSICAL REVIEW E, 2003, 67 (03) :8
[3]  
Berne BJ, 2000, Dynamic Light Scattering: With Applications to Chemistry, Biology, and Physics
[4]   Direct experimental evidence of a growing length scale accompanying the glass transition [J].
Berthier, L ;
Biroli, G ;
Bouchaud, JP ;
Cipelletti, L ;
El Masri, D ;
L'Hôte, D ;
Ladieu, F ;
Pierno, M .
SCIENCE, 2005, 310 (5755) :1797-1800
[5]   Anomalous dynamical light scattering in soft glassy gels [J].
Bouchaud, JP ;
Pitard, E .
EUROPEAN PHYSICAL JOURNAL E, 2001, 6 (03) :231-236
[6]   ANOMALOUS DIFFUSION IN DISORDERED MEDIA - STATISTICAL MECHANISMS, MODELS AND PHYSICAL APPLICATIONS [J].
BOUCHAUD, JP ;
GEORGES, A .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1990, 195 (4-5) :127-293
[7]   Enhanced translation of probe molecules in supercooled o-terphenyl: Signature of spatially heterogeneous dynamics? [J].
Cicerone, MT ;
Ediger, MD .
JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (18) :7210-7218
[8]   Universal non-diffusive slow dynamics in aging soft matter [J].
Cipelletti, L ;
Ramos, L ;
Manley, S ;
Pitard, E ;
Weitz, DA ;
Pashkovski, EE ;
Johansson, M .
FARADAY DISCUSSIONS, 2003, 123 :237-251
[9]   Universal aging features in the restructuring of fractal colloidal gels [J].
Cipelletti, L ;
Manley, S ;
Ball, RC ;
Weitz, DA .
PHYSICAL REVIEW LETTERS, 2000, 84 (10) :2275-2278
[10]   Supercooled liquids and the glass transition [J].
Debenedetti, PG ;
Stillinger, FH .
NATURE, 2001, 410 (6825) :259-267