The synthesis of dimeric porphyrins linked by a ferrocene

被引：56

作者：

Burrell, AK ^{[1
]}

Campbell, W ^{[1
]}

Officer, DL ^{[1
]}

机构：

[1] MASSEY UNIV,DEPT CHEM,PALMERSTON NORTH,NEW ZEALAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(97)00049-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterisation of dimeric porphyrins linked via a ferrocene are reported The porphyrins are prepared using a Wittig reaction of a tetraphenylporphyrin-derived phosphonium salt and 1,1'-diformylferrocene. The reaction can be carried out in a stepwise manner to enable the preparation of heterobimetallic complexes. (C) 1997, Elsevier Science Ltd.

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页码：1249 / 1252

页数：4

相关论文

共 13 条

[1] THE PREPARATION OF NOVEL PORPHYRINS AND BIS(PORPHYRINS) USING PALLADIUM CATALYZED COUPLING REACTIONS [J].

ARNOLD, DP ;

NITSCHINSK, LJ .

TETRAHEDRON LETTERS, 1993, 34 (04) :693-696

[2] A NOVEL PORPHYRIN-FERROCENE-QUINONE LINKED MOLECULE [J].

BEER, PD ;

KUREK, SS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 366 (1-2) :C6-C8

[3] THE SYNTHESIS AND ELECTROCHEMISTRY OF A NOVEL FERROCENE BIS-PORPHYRIN MOLECULE [J].

BEER, PD ;

KUREK, SS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 336 (1-2) :C17-C21

[4] SPECTRAL AND ELECTROCHEMICAL ANION SENSING BY A NOVEL 5,10,15,20-TETRAKIS(R-SUBSTITUTED) PORPHYRIN RECEPTOR (R=C6H4NHC(O)C5H4COC5H5+PF6-) [J].

BEER, PD ;

DREW, MGB ;

HESEK, D ;

JAGESSAR, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (11) :1187-1189

[5] THE SYNTHESIS OF BUTADIENE-BRIDGED PORPHYRIN DIMERS AND STYRYL PORPHYRINS USING A PORPHYRIN-DERIVED WITTIG REAGENT [J].

BONFANTINI, EE ;

OFFICER, DL .

TETRAHEDRON LETTERS, 1993, 34 (52) :8531-8534

[6] SYNTHESIS AND CHARACTERIZATION OF A SUPEROXO COMPLEX OF THE DICOBALT COFACIAL DIPORPHYRIN [(MU-O2)CO2(DPB)(1,5-DIPHENYLIMIDAZOLE)2][PF6], THE STRUCTURE OF THE PARENT DICOBALT DIPORPHYRIN CO2(DPB), AND A NEW SYNTHESIS OF THE FREE-BASE COFACIAL DIPORPHYRIN H-4(DPB) [J].

COLLMAN, JP ;

HUTCHISON, JE ;

LOPEZ, MA ;

TABARD, A ;

GUILARD, R ;

SEOK, WK ;

IBERS, JA ;

LHER, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :9869-9877

[7] A SYNTHETIC ANALOG FOR THE OXYGEN-BINDING SITE IN CYTOCHROME-C-OXIDASE [J].

COLLMAN, JP ;

HERRMANN, PC ;

BOITREL, B ;

ZHANG, XM ;

EBERSPACHER, TA ;

FU, L ;

WANG, JL ;

ROUSSEAU, DL ;

WILLIAMS, ER .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) :9783-9784

[8] HIGHLY CONJUGATED, ACETYLENYL BRIDGED PORPHYRINS - NEW MODELS FOR LIGHT-HARVESTING ANTENNA SYSTEMS [J].

LIN, VSY ;

DIMAGNO, SG ;

THERIEN, MJ .

SCIENCE, 1994, 264 (5162) :1105-1111

[9]

Loim NM, 1996, MENDELEEV COMMUN, P46

[10]

OLUKA A, 1993, CHEM LETT, P161