A novel anode material LiVMoO6 for rechargeable lithium-ion batteries

被引:13
作者
Liu, RS [1 ]
Wang, CY
Drozd, VA
Hu, SF
Sheu, HS
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[2] Natl Nano Device Labs, Hsinchu 300, Taiwan
[3] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
关键词
D O I
10.1149/1.2119629
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mixed transition metal oxide LiVMoO6 was synthesized by the solid-state reaction method and was exploited as an anode material for use in rechargeable lithium-ion batteries. The electrochemical characteristics of the prepared electrodes assembled in coin cells were investigated in terms of half-cell performance. It was observed that the cell exhibits three discharge plateaus. The total discharge capacity, averaged over several test runs, is about 1250 mAh/g. The mechanism of electrochemical reaction of LiVMoO6 with Li was studied in situ by the synchrotron X-ray diffraction method. It was found that LiVMoO6 undergoes irreversible decomposition during the first discharge. (c) 2005 The Electrochemical Society.
引用
收藏
页码:A650 / A653
页数:4
相关论文
共 22 条
[1]   Synthesis, structure and lithium intercalation reaction in LiMoVO6 brannerite-type materials [J].
Amdouni, N ;
Zarrouk, H ;
Soulette, F ;
Julien, CM .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (09) :2374-2380
[2]   Corrosion of lithiuim-ion battery current collectors [J].
Braithwaite, JW ;
Gonzales, A ;
Nagasubramanian, G ;
Lucero, SJ ;
Peebles, DE ;
Ohlhausen, JA ;
Cieslak, WR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :448-456
[3]   Lithium insertion into host materials: the key to success for Li ion batteries [J].
Broussely, M ;
Biensan, P ;
Simon, B .
ELECTROCHIMICA ACTA, 1999, 45 (1-2) :3-22
[4]   Instability of brannerite cathode materials upon lithium insertion [J].
Cushing, BL ;
Kang, SH ;
Goodenough, JB .
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (07) :875-879
[5]   Study of the reactivity mechanism of M3B2O6 (with M = Co, Ni, and Cu) toward lithium [J].
Débart, A ;
Revel, B ;
Dupont, L ;
Montagne, L ;
Leriche, JB ;
Touboul, M ;
Tarascon, JM .
CHEMISTRY OF MATERIALS, 2003, 15 (19) :3683-3691
[6]   Synthesis and electrochemical properties of amorphous vanadates of general formula RVO4 (R = In, Cr, Fe, Al, Y) vs. Li [J].
Denis, S ;
Baudrin, E ;
Touboul, M ;
Tarascon, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (12) :4099-4109
[7]   A new charge density wave oxide, LiVMoO5 and its tungsten analogue obtained by topotactic reduction of LiVMO(6) (M=Mo,W) brannerites [J].
Gopalakrishnan, J ;
Bhuvanesh, NSP ;
Vijayaraghavan, R ;
Vasanthacharya, NY .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (02) :307-310
[8]   An update on the reactivity of nanoparticles Co-based compounds towards Li [J].
Grugeon, S ;
Laruelle, S ;
Dupont, L ;
Tarascon, JM .
SOLID STATE SCIENCES, 2003, 5 (06) :895-904
[9]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[10]   A novel approach to exploit LiFePO4 compound as an ambient temperature high capacity anode material for rechargeable lithium batteries [J].
Kalaiselvi, N ;
Doh, CH ;
Park, CW ;
Moon, SI ;
Yun, MS .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (11) :1110-1113