Enhanced microwave absorbing properties of 2.5D SiCf/SiC composites fabricated by a modified precursor infiltration and pyrolysis process

被引:44
作者
Mu, Yang [1 ]
Zhou, Wancheng [1 ]
Hu, Yang [1 ]
Ding, Donghai [2 ]
Luo, Fa [1 ]
Qing, Yuchang [1 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Xian 710072, Shaanxi, Peoples R China
[2] Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Xian 710055, Shaanxi, Peoples R China
关键词
SiCf/SiC composites; Microwave absorbing property; Precursor infiltration and pyrolysis; Cross-linking; Decarbonization; SIC MATRIX COMPOSITES; DIELECTRIC-PROPERTIES; MECHANICAL-PROPERTIES; SHIELDING PROPERTIES; PIP; CERAMICS; MICROSTRUCTURE; INTERPHASE; OXIDATION; POWDER;
D O I
10.1016/j.jallcom.2015.03.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SiCf/SiC composites with enhanced microwave absorbing properties were prepared using a modified precursor infiltration and pyrolysis (PIP) process by the appropriate thermal cross-linking of polycarbosilane (PCS) precursor and decarbonization of SiC fibers. The results reveal that the complex permittivity of both SiC fibers and SiC matrix decreases to a suitable level after the treatments, thus the final composites show an optimized complex permittivity that favors for the impedance matching and attenuation characteristic. The reduction of complex permittivity is mainly attributed to the consumption of excessive carbon in these components by the introduced oxygen during these processes, which also results in the decline of flexural strength of the composites from 266 MPa to 223 MPa. The composites without treatments exhibit a poor reflection loss (RL) value less than -5 dB in the frequency range of 8.2-18 GHz. However, the minimum RL value of the composites with a thickness of 3.1 mm after treatments reaches -23.5 dB and the bandwidth below -10 dB extends to 5.9 GHz. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:261 / 266
页数:6
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