Valorization of biomass waste to engineered activated biochar by microwave pyrolysis: Progress, challenges, and future directions

被引:559
作者
Foong, Shin Ying [1 ,2 ,3 ]
Liew, Rock Keey [4 ]
Yang, Yafeng [1 ]
Cheng, Yoke Wang [5 ]
Yek, Peter Nai Yuh [6 ]
Mahari, Wan Adibah Wan [2 ,3 ]
Lee, Xie Yi [2 ,3 ]
Han, Chai Sean [2 ,3 ]
Vo, Dai-Viet N. [7 ]
Quyet Van Le [8 ]
Aghbashlo, Mortaza [9 ]
Tabatabaei, Meisam [10 ,11 ]
Sonne, Christian [12 ]
Peng, Wanxi [1 ]
Lam, Su Shiung [1 ,2 ,3 ]
机构
[1] Henan Agr Univ, Henan Prov Engn Res Ctr Biomass Value Added Prod, Sch Forestry, Zhengzhou 450002, Peoples R China
[2] Univ Malaysia Terengganu, Inst Trop Aquaculture & Fisheries AKUATROP, Pyrolysis Technol Res Grp, Kuala Nerus 21030, Terengganu, Malaysia
[3] Univ Malaysia Terengganu, Inst Trop Biodivers & Sustainable Dev Bio D Tropi, Kuala Nerus 21030, Terengganu, Malaysia
[4] NV WESTERN PLT, 208B,Jalan Macalister, Georgetown 10400, Pulau Pinang, Guyana
[5] Univ Teknol PETRONAS, Ctr Biofuel & Biochem Res, Inst Self Sustainable Bldg, Seri Iskandar 32610, Perak, Malaysia
[6] Univ Coll Technol Sarawak, Dept Engn, Sarawak 96000, Malaysia
[7] Nguyen Tat Thanh Univ, Ctr Excellence Green Energy & Environm Nanomat CE, 300A Nguyen Tat Thanh,Dist 4, Ho Chi Minh City 755414, Vietnam
[8] Duy Tan Univ, Inst Res & Dev, Da Nang 550000, Vietnam
[9] Univ Tehran, Coll Agr & Nat Resources, Fac Agr Engn & Technol, Dept Mech Engn Agr Machinery, Karaj, Iran
[10] Univ Teknol MARA UiTM, Fac Plantat & Agrotechnol, Shah Alam 40450, Selangor, Malaysia
[11] AREEO, Dept Microbial Biotechnol, ABRII, Karaj, Iran
[12] Aarhus Univ, Arctic Res Ctr, Dept Biosci, Frederiksborgvej 399,POB 358, DK-4000 Roskilde, Denmark
关键词
Biomass pyrolysis; Microwave heating; Waste valorization/recycling; Energy recovery; Biochar; Sustainable production; PALM KERNEL SHELL; HIGH-SURFACE-AREA; ASSISTED CO-PYROLYSIS; OIL MILL EFFLUENT; HIGH-TEMPERATURE PYROLYSIS; BIO-OIL; VACUUM PYROLYSIS; POROUS CARBON; CHEMICAL ACTIVATION; RICE HUSK;
D O I
10.1016/j.cej.2020.124401
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Biomass waste represents the promising surrogate of fossil fuels for energy recovery and valorization into value-added products. Among thermochemical conversion techniques of biomass, pyrolysis appears to be most alluring owing to its low pollutant emission and diverse products formation. The current pyrolysis applications for valorization of biomass waste is reviewed, covering the key concepts, pyrolysis mode, operating parameters and products. To date, existing types of pyrolysis include conventional pyrolysis (poor heat transfer due to non- selective heating), vacuum pyrolysis (lower process temperature because of vacuum), solar pyrolysis (entirely "green" with solar-powered), and a newly touted microwave pyrolysis. In microwave pyrolysis of biomass, the heat transfer is more efficient as the heat is generated within the core of material by the interaction of microwave with biomass. The plausible mechanisms of microwave heating are dipole polarization, ionic conduction and interfacial polarization. The lack of top-tier reactor design is identified as the main obstacle that impedes the commercialization of microwave pyrolysis in biomass recycling. Based on the existing works, it is surmised that microwave pyrolysis of biomass produces solid biochar as a main product. To confront the great market demand of activated biochar, it is proposed that the solid char could be upgraded into engineered activated biochar with desirable properties for wide application in pollution control, catalysis and energy storage. Hence, the production of engineered activated biochar from microwave pyrolysis process and its applications are reviewed and explicitly discussed to fill the research gap, and the key implications for future development are highlighted.
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页数:20
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