New Iron(III) Bis(acetylide) Compounds Based on the Iron Cyclam Motif

被引：25

作者：

Cao, Zhi ^{[1
]}

Forrest, William P. ^{[1
]}

Gao, Yang ^{[1
]}

Fanwick, Phillip E. ^{[1
]}

Zhang, Yang ^{[1
]}

Ren, Tong ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 16期

基金：

美国国家科学基金会;

关键词：

ORGANOMETALLIC COMPOUNDS; MOLECULAR WIRES; COMPLEXES; CARBON; ACETYLIDES; TRANSPORT; CHEMISTRY; TERMINI;

D O I：

10.1021/ic200836v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New trans-[Fe(cyclam) (C equivalent to CR)(2)]OTf compounds 2a/2b [cyclam = 1,4,8,11-tetraazacyclotetradecane, R = (SiPr3)-Pr-i (a) or Ph (b), and OTf= trifluoromethanesulfonate] were prepared from the reaction between trans-[Fe(cyclam)(OTf)(2)]OTf(1) and LiC equivalent to CR. The trans arrangement of the acetylide ligands in 2 was established from the X-ray diffraction study of 2a, and the density functional theory calculations revealed significant d pi-pi(C equivalent to C) interactions.

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收藏

页码：7364 / 7366

页数：3

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