Cleavage of carbon-sulfur bonds in the synthesis of alpha-haloalkyl carbonates

被引：2
|
作者：
Hatlelid, J
Benneche, T
Undheim, K
机构：
[1] UNIV OSLO,DEPT CHEM,N-0315 OSLO,NORWAY
[2] UNIV OSLO,DEPT PHARM,N-0316 OSLO,NORWAY
来源：
ACTA CHEMICA SCANDINAVICA | 1996年 / 50卷 / 11期
关键词：
D O I：
10.3891/acta.chem.scand.50-1041
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
alpha-Chloroalkyl and alpha-bromoalkyl carbonates have been prepared by cleavage of alpha-arylthioalkyl carbonates with sulfuryl chloride or bromine, respectively. The alpha-arylthioalkyl carbonates are prepared by reaction of the hemithioacetal 1 with chloroformates or by a destannylative tin-Pummerer rearrangement of alpha-stannyl sulfoxides.
引用
收藏
页码：1041 / 1044
页数：4
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