The impact of hydrophobic coating on the performance of carbon nanotube bucky-paper membranes in membrane distillation

被引:71
作者
Dumee, Ludovic [1 ,2 ]
Campbell, Jos L. [3 ]
Sears, Kallista [1 ]
Schuetz, Juerg [1 ]
Finn, Niall [1 ]
Duke, Mikel [2 ]
Gray, Stephen [2 ]
机构
[1] CSIRO Mat Sci & Engn, Clayton, Vic 3168, Australia
[2] Victoria Univ, Melbourne, Vic 8001, Australia
[3] RMIT Univ, Sch Appl Sci, Adv Mat & Ind Chem Grp, Melbourne, Vic, Australia
关键词
Carbon nanotube bucky-paper; Poly(tetra fluoro ethylene) composite; Membrane distillation; Desalination; POLY(VINYL ALCOHOL); MASS-TRANSPORT; PERVAPORATION; FABRICATION; WATER;
D O I
10.1016/j.desal.2011.02.046
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Self-supporting bucky-papers membranes were processed from chemical vapour deposition grown carbon nanotubes and coated with a thin layer of poly(tetra-fluoro-ethylene) (PTFE) to enhance their hydrophobicity and improve their mechanical stability over time, without drastically changing their average pore size and porosity. Contact angles and bubble point pressure were respectively increased by 23% and 28%. After coating the membranes were tested in a direct contact membrane distillation setup at various feed temperatures with 35 g/L NaCl feed solution and coated samples exhibited improved lifespan and water vapour permeability at salt rejection higher than 99%. The bucky-paper membranes were also compared with commercial PTFE membranes of similar properties. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:64 / 67
页数:4
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