Recent advances in supported ionic liquid membrane technology

被引：321

作者：

Lozano, L. J. ^{[1
]}

Godinez, C. ^{[1
]}

de los Rios, A. P. ^{[1
]}

Hernandez-Fernandez, F. J. ^{[1
]}

Sanchez-Segado, S. ^{[1
]}

Alguacil, F. J. ^{[2
]}

机构：

[1] Tech Univ Cartagena, Dept Chem & Environm Engn, E-30202 Murcia, Spain

[2] CSIC, CENIM, Spanish Natl Res Council, Natl Ctr Met Res, E-28040 Madrid, Spain

来源：

JOURNAL OF MEMBRANE SCIENCE | 2011年 / 376卷 / 1-2期

关键词：

Supported ionic liquid membrane; Ionic liquid; Membrane transport; Operational stability; Mechanism; Green solvent; SELECTIVE SIMULTANEOUS SEPARATION; ENVIRONMENTAL WATER SAMPLES; PRESSURE CARBON-DIOXIDE; TRANSESTERIFICATION REACTION; FACILITATED TRANSPORT; GAS SEPARATIONS; HYDROCARBON SOLUBILITIES; KINETIC RESOLUTION; ORGANIC-COMPOUNDS; LACTIC-ACID;

D O I：

10.1016/j.memsci.2011.03.036

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Novel processes based on supported liquid membranes have been proposed as effective methods for the selective separation of different chemical species in dilute streams, such as metal ions, organic compounds or biologically important compounds and gas mixtures. However, the industrial use of supported liquid membranes based on conventional liquids is limited by their relative instability and short lifetime. The use of ionic liquids as a liquid membrane phase could overcome these inconveniences due to their negligible vapour pressure and the possibility of minimizing their solubility in the surrounding phases by adequate selection of the cation and anion. The possibility of designing suitable ionic liquids for specific separation problems has also opened up new potential fields of industrial application of supported ionic liquid membranes. In this review an overview is given of recent advances in supported membranes based on ionic liquids, including issues such as methods of preparation, transport mechanisms, configurations, stability, fields of application and process intensification using supported ionic liquid membranes. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1 / 14

页数：14

共 115 条

[1] Pseudo-emulsion based hollow fiber with strip dispersion pertraction of iron(III) using (PJMTH+)2(SO42-) ionic liquid as carrier [J].

Alguacil, F. J. ;

Alonso, M. ;

Lopez, F. A. ;

Lopez-Delgado, A. ;

Padilla, I. ;

Tayibi, H. .

CHEMICAL ENGINEERING JOURNAL, 2010, 157 (2-3) :366-372

[2] Transport of Americium(III) through a supported liquid membrane containing N,N,N′,N′-tetraoctyl-3-oxapentane, diamide (TODGA) in n-dodecane as the carrier [J].

Ansari, S. A. ;

Mohapatra, P. K. ;

Prabhu, D. R. ;

Manchanda, V. K. .

JOURNAL OF MEMBRANE SCIENCE, 2006, 282 (1-2) :133-141

[3] Synthesis and performance of polymerizable room-temperature ionic liquids as gas separation membranes [J].

Bara, Jason E. ;

Lessmann, Sonja ;

Gabriel, Christopher J. ;

Hatakeyama, Evan S. ;

Noble, Richard D. ;

Gin, Douglas L. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (16) :5397-5404

[4] Gas separations in fluoroalkyl-functionalized room-temperature ionic liquids using supported liquid membranes [J].

Bara, Jason E. ;

Gabriel, Christopher J. ;

Carlisle, Trevor K. ;

Camper, Dean E. ;

Finotello, Alexia ;

Gin, Douglas L. ;

Noble, Richard D. .

CHEMICAL ENGINEERING JOURNAL, 2009, 147 (01) :43-50

[5] Acute and chronic toxicity of imidazolium-based ionic liquids on Daphnia magna [J].

Bernot, RJ ;

Brueseke, MA ;

Evans-White, MA ;

Lamberti, GA .

ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 2005, 24 (01) :87-92

[6] Physical-chemical and electrical characterizations of membranes modified with room temperature ionic liquids: Age effect [J].

Bijani, S. ;

Fortunato, R. ;

Martinez de Yuso, M. V. ;

Heredia-Guerrero, F. A. ;

Rodriguez-Castellon, E. ;

Coelhoso, I. ;

Crespo, J. ;

Benavente, J. .

VACUUM, 2009, 83 (10) :1283-1286

[7] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[8]

Branco LC, 2002, CHEM-EUR J, V8, P3865, DOI 10.1002/1521-3765(20020902)8:17<3865::AID-CHEM3865>3.0.CO

[9]

2-L

[10]

Branco LC, 2002, ANGEW CHEM INT EDIT, V41, P2771, DOI 10.1002/1521-3773(20020802)41:15<2771::AID-ANIE2771>3.0.CO

← 1 2 3 4 5 6 7 8 9 10 →