Chiral channels in a 3-D network of self-assembled tetranuclear copper(II) aggregates

被引：45

作者：

Fragoso, A

Kahn, ML

Castiñeiras, A

Sutter, JP ^{[1
]}

Olivier, K

Cao, R

机构：

[1] Inst Chim Mat Condensee Bordeaux, Lab Sci Mol, CNRS, UPR 9048, F-33608 Pessac, France

[2] Univ Havana, Fac Chem, Lab Bioinorgan Chem, Havana 10400, Cuba

[3] Univ Santiago de Compostela, Fac Pharm, Dept Inorgan Chem, Santiago De Compostela 15, Spain

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 16期

关键词：

D O I：

10.1039/b002360o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sugar-substituted ligand allowed for the synthesis of chiral Cu(II) tetranuclear aggregates which assemble via H-bonding in a 3D-network containing hydrophobic helical channels.

引用

页码：1547 / 1548

页数：2

共 25 条

[11]

MURRAY KS, 1995, ADV INORG CHEM, V43, P261

[12] Cluster assembly by hydrogen bonds:: Channel structure of Cu4L4 cubanes [J].

Oshio, H ;

Saito, Y ;

Ito, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) :2673-2675

[13]

Osterloh F, 1999, ANGEW CHEM INT EDIT, V38, P2066, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<2066::AID-ANIE2066>3.0.CO

[14]

2-K

[15] Functional mimics of superoxide dismutase enzymes as therapeutic agents [J].

Riley, DP .

CHEMICAL REVIEWS, 1999, 99 (09) :2573-2587

[16]

Rojo J, 1999, EUR J INORG CHEM, P517

[17]

Saalfrank RW, 1998, CHEM-EUR J, V4, P1305

[18]

SORELL TN, 1989, TETRAHEDRON, V45, P3

[19] The [Cu-2(O2CMe)(4)(H2O)(2)]/(py)(2)CO system as the source of an unusual heptanuclear complex and a novel dodecanuclear ''Flywheel'' cluster [J].

Tangoulis, V ;

Raptopoulou, CP ;

Paschalidou, S ;

Bakalbassis, EG ;

Perlepes, SP ;

Terzis, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (10) :1083-1085

[20] Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets [J].

Thomas, L ;

Lionti, F ;

Ballou, R ;

Gatteschi, D ;

Sessoli, R ;

Barbara, B .

NATURE, 1996, 383 (6596) :145-147

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