Anionic [4+2] cycloaddition strategy in the regiospecific synthesis of carbazoles: formal synthesis of ellipticine and murrayaquinone A

被引：53

作者：

Mal, Dipakranjan ^{[1
]}

Senapati, Bidyut Kumar ^{[1
]}

Pahari, Pallab ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

TETRAHEDRON | 2007年 / 63卷 / 18期

关键词：

carbazole quinone; anionic cycloaddition; furoindolone;

D O I：

10.1016/j.tet.2007.02.060

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anionic [4+2] cycloaddition of furoindolones (e.g., 7 and 10) has been developed as an effective means to the synthesis of carbazoles. This reaction has been shown to be feasible with a wide variety of Michael acceptors to give carbazoles and fused carbazoles in good yields. The scope and limitations of the reaction have been briefly studied. The nature of N-protection of the furoindolones (cf. 7) plays a major role in the success of annulation. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：3768 / 3781

页数：14

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