The rotation and the phase transition in solid C-60

被引：0

作者：

Xu, ZJ ^{[1
]}

Yan, JM ^{[1
]}

机构：

[1] CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA

来源：

CHINESE JOURNAL OF CHEMISTRY | 1996年 / 14卷 / 06期

关键词：

fullerene; C-60; molecular rotation; phase transition;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction between C-60's in solid C-60 has been calculated by (exp-6-1) potential, and the cause and the controlled factor of the high rapid rotations of C-60's were discussed. In order to describe the disordered degree of C-60 rotation, an equivalent M is introduced. The phase transitions at the similar to 260 K and at the similar to 90 K are studied from the viewpoint of C-60 rotation. The potential barriers of the ordered rotation below the similar to 260 K and the disordered rotation above the similar to 260 K have been given, and the effect of the external pressure on the temperature of phase transition has also been given.

引用

页码：481 / 489

页数：9

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