Catalytic Oxidation of 5-Hydroxymethylfurfural into 2,5-Diformylfuran Over Vanadyl and Cupric Immobilized on Amino-Functionalized MCM-41

被引：2

作者：

Liu, Chenlu ^{[1
]}

Liao, Longfei ^{[1
]}

Li, Zengyong ^{[1
]}

Liu, Ying ^{[1
]}

Wu, Shubin ^{[1
]}

Zhuang, Junping ^{[1
]}

机构：

[1] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

JOURNAL OF BIOBASED MATERIALS AND BIOENERGY | 2017年 / 11卷 / 05期

关键词：

5-Hydroxymethylfurfural; 2,5-Diformylfuran; Mesoporous MCM-41; Aerobic Oxidation; AEROBIC OXIDATION; AQUEOUS-SOLUTION; BIOMASS; ACID; CHEMICALS; ISOMERIZATION; DERIVATIVES; EPOXIDATION; CONVERSION; ALCOHOL;

D O I：

10.1166/jbmb.2017.1698

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Mesoporous MCM-41 was amino-functionalized to immobilize cupric (Cu2+) and vanadyl (VO2+) for preparing MCM-NH2-Cu2+ and MCM-NH2-VO2+ co-catalysts. The as-prepared two catalysts had been characterized by XRD, N-2 adsorption-desorption, FT-IR, XPS and TEM. The catalytic performance of MCM-NH2-VO2+ in HMF oxidation could be significantly promoted by using MCM-NH2-Cu2+ as the co-catalysts. Several critical reaction parameters had been investigated, and it indicated that the highest conversion of 5-hydroxymethylfurfural (HMF) obtained was 98.1% at 110 degrees C in toluene with an optimal 2,5-diformylfuran (DFF) yield of 61.2%. Particularly, the MCM-NH2-Cu2+ and MCM-NH2-VO2+ catalyst exhibited great stability and can be reused and showed no significant loss of their catalytic activities.

引用

页码：414 / 423

页数：10

共 38 条

[1] The selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using heterogeneous catalysts [J].

Alamillo, Ricardo ;

Tucker, Mark ;

Chia, Mei ;

Pagan-Torres, Yomaira ;

Dumesic, James .

GREEN CHEMISTRY, 2012, 14 (05) :1413-1419

[2] Renewable resources based polymers: Synthesis and characterization of 2,5-diformylfuran-urea resin [J].

Amarasekara, Ananda S. ;

Green, Dalkeith ;

Williams, LaToya D. .

EUROPEAN POLYMER JOURNAL, 2009, 45 (02) :595-598

[3] Etherification and reductive etherification of 5-(hydroxymethyl)furfural: 5-(alkoxymethyl)furfurals and 2,5-bis(alkoxymethyl)furans as potential bio-diesel candidates [J].

Balakrishnan, Madhesan ;

Sacia, Eric R. ;

Bell, Alexis T. .

GREEN CHEMISTRY, 2012, 14 (06) :1626-1634

[4] Selective oxidation of 5-hydroxymethyl-2-furaldehyde to furan-2,5-dicarboxaldehyde by catalytic systems based on vanadyl phosphate [J].

Carlini, C ;

Patrono, P ;

Galletti, AMR ;

Sbrana, G ;

Zima, V .

APPLIED CATALYSIS A-GENERAL, 2005, 289 (02) :197-204

[5] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[6] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[7] Structure in vitro activity relationships of pentamidine analogues and dication-substituted bis-benzimidazoles as new antifungal agents [J].

Del Poeta, M ;

Schell, WA ;

Dykstra, CC ;

Jones, S ;

Tidwell, RR ;

Czarny, A ;

Bajic, M ;

Kumar, A ;

Boykin, D ;

Perfect, JR .

ANTIMICROBIAL AGENTS AND CHEMOTHERAPY, 1998, 42 (10) :2495-2502

[8] Oxidation of 5-hydroxymethylfurfural to maleic anhydride with molecular oxygen [J].

Du, Zhongtian ;

Ma, Jiping ;

Wang, Feng ;

Liu, Junxia ;

Xu, Jie .

GREEN CHEMISTRY, 2011, 13 (03) :554-557

[9]

Evans J., 2003, J PHYS CHEM, V104, P10271

[10] Catalytic Conversion of Biomass: Challenges and Issues [J].

Gallezot, Pierre .

CHEMSUSCHEM, 2008, 1 (8-9) :734-737

← 1 2 3 4 →