Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents

被引：0

作者：

Golubev, A., V ^{[1
]}

Kubasov, A. S. ^{[1
]}

Bykov, A. Yu ^{[1
]}

Zhizhin, K. Yu ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

DOKLADY CHEMISTRY | 2021年 / 500卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

closo-decaborate anion; boron clusters; sulfonium derivatives; halogenation;

D O I：

10.1134/S0012500821100025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of sulfonium closo-decaborate derivatives containing carboxyl groups with sulfuryl chloride SO2Cl2 as a halogenating agent was studied. The reaction gave fully halogenated derivatives of the closo-decaborate anion, (n-Bu4N)[2-B10Cl9SR2] (R = -CH2COOEt, -CH2COOH), which was confirmed by B-11, H-1, and C-13 NMR and IR spectral data. The structure of the [2-B10Cl9S(CH2COOEt)(2)](-) anion was established using single crystal X-ray diffraction.

引用

页码：205 / 208

页数：4

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