Intermolecular nitroso Diels-Alder cycloaddition of α-acetoxynitroso derivatives in aqueous medium

被引：29

作者：

Calvet, G ^{[1
]}

Guillot, R ^{[1
]}

Blanchard, N ^{[1
]}

Kouklovsky, C ^{[1
]}

机构：

[1] Inst Chim Mol & Mat Orsay, UMR CNRS 8615, Lab Synth Subst Nat, F-91400 Orsay, France

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 24期

关键词：

D O I：

10.1039/b513397a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder cycloadditions of the alpha-acetoxynitroso dienophile 1 in water are reported. The rapid and high yielding synthesis of structurally diverse 3,6-dihydro-1,2-oxazines complements the straightforward elaboration of aminoalcohols obtained from the alpha-acetoxynitroso derivative 1 in anhydrous medium. A rationale for this solvent-dependent product distribution is proposed.

引用

页码：4395 / 4401

页数：7

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