Derivatization and Functionalization of Molecular Matrix by Hydrogen Bond at Liquid-Solid Interface

被引：6
|
作者：
Zhang, Rui [1 ]
Shen, Yongtao [1 ]
Zeng, Qingdao [1 ]
Wang, Chen [1 ]
机构：
[1] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2011年 / 11卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Derivatization; Functionalization; Self-Assembly; Scanning Tunneling Microscopy; NETWORKS; SURFACES; NANOSTRUCTURES; RECOGNITION; SELECTION; TEMPLATE;
D O I：
10.1166/jnn.2011.4980
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Derivatization of porous molecular network formed by 1,3,5-tris (10-carboxydecyloxy) benzene (TCDB) via hydrogen bond interaction is demonstrated in this work. With the introduction of 4,4'-bipyridyl (Bpy) the TCDB network is observed to form a heteromolecular cluster, TCDB6-Bpy(6), on highly oriented pyrolytic graphite (HOPG) surface under ambient conditions using scanning tunneling microscopy (STM). The derivatized network is further observed to accommodate single guest species such as coronene to form a well-ordered ternary two-dimensional (2D) structure.
引用
收藏
页码：10111 / 10115
页数：5
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