Influence of Deposition Conditions on Silicon Nanoclusters in Silicon Nitride Films Grown by Laser-Assisted CVD Method

被引:1
作者
Tsai, Tai-Cheng [1 ]
Lou, Li-Ren [1 ,2 ]
Lee, Ching-Ting [1 ,2 ]
机构
[1] Natl Cheng Kung Univ, Dept Elect Engn, Inst Microelect, Tainan 701, Taiwan
[2] Natl Cheng Kung Univ, Adv Optoelect Technol Ctr, Tainan 701, Taiwan
关键词
Laser-assisted CVD(LACVD) system; photoluminescence (PL); quantum confinement effect; Si nanoclusters; silicon nitride matrix; QUANTUM DOTS; PHOTOLUMINESCENCE; LUMINESCENCE; ABSORPTION;
D O I
10.1109/TNANO.2009.2036609
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Crystalline-silicon-nanocluster-embedded silicon nitride films were deposited at low temperature using a laser-assisted CVD (LACVD) system with various reactant gas flow rates and assisting laser power densities. The photoluminescence (PL) performances of the resultant films were studied, showing a systematic spectra blue shift, and the enhancement of PL intensity with the increase of the reactant NH3/SiH4 gas flow rate ratio and the assisting laser power density used in the film deposition. The spectra blue shift can be ascribed to the decrease of the size of the nanoclusters in the films. It is also deduced that both the reduction of the amount of nonradiative centers in the nanoclusters and the increase of the number density of the nanoclusters in the film are responsible for the enhancement of the PL intensity. The film growth process is also briefly discussed.
引用
收藏
页码:197 / 202
页数:6
相关论文
共 18 条
[1]   SILICON QUANTUM WIRE ARRAY FABRICATION BY ELECTROCHEMICAL AND CHEMICAL DISSOLUTION OF WAFERS [J].
CANHAM, LT .
APPLIED PHYSICS LETTERS, 1990, 57 (10) :1046-1048
[2]   Schottky mechanism for Ni/Au contact with chlorine-treated n-type GaN layer [J].
Chen, Po-Sung ;
Lee, Tsung-Hsin ;
Lai, Li-Wen ;
Lee, Ching-Ting .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (02)
[3]   Modified Raman confinement model for Si nanocrystals [J].
Faraci, G ;
Gibilisco, S ;
Russo, P ;
Pennisi, AR ;
La Rosa, S .
PHYSICAL REVIEW B, 2006, 73 (03)
[4]   Correlation between electroluminescence and structural properties of Si nanoclusters [J].
Irrera, A ;
Iacona, F ;
Franzò, G ;
Boninelli, S ;
Pacifici, D ;
Miritello, M ;
Spinella, C ;
Sanfilippo, D ;
Di Stefano, G ;
Fallica, PG ;
Priolo, F .
OPTICAL MATERIALS, 2005, 27 (05) :1031-1040
[5]   Photoluminescence of silicon quantum dots in silicon nitride grown by NH3 and SIH4 -: art. no. 091908 [J].
Kim, BH ;
Cho, CH ;
Kim, TW ;
Parka, NM ;
Sung, GY ;
Park, SJ .
APPLIED PHYSICS LETTERS, 2005, 86 (09) :1-3
[6]   Transparent conducting aluminum-doped zinc oxide thin films for organic light-emitting devices [J].
Kim, H ;
Gilmore, CM ;
Horwitz, JS ;
Piqué, A ;
Murata, H ;
Kushto, GP ;
Schlaf, R ;
Kafafi, ZH ;
Chrisey, DB .
APPLIED PHYSICS LETTERS, 2000, 76 (03) :259-261
[7]   Raman, photoluminescence and optical absorption studies on nanocrystalline silicon [J].
Mishra, P ;
Jain, KP .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2002, 95 (03) :202-213
[8]   LUMINESCENCE OF NANOMETER-SIZED AMORPHOUS-SILICON NITRIDE SOLIDS [J].
MO, CM ;
ZHANG, LD ;
XIE, CY ;
WANG, T .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (10) :5185-5188
[9]  
NEGRO LD, 2006, APPL PHYS LETT, V88
[10]  
Park NM, 2002, CHEM VAPOR DEPOS, V8, P254, DOI 10.1002/1521-3862(20021203)8:6<254::AID-CVDE254>3.0.CO