Hierarchical Interactions and Their Influence upon the Adsorption of Organic Molecules on a Graphene Film

被引：54

作者：

Roos, Michael ^{[1
]}

Kuenzel, Daniela ^{[2
]}

Uhl, Benedikt ^{[1
]}

Huang, Hsin-Hui ^{[1
]}

Alves, Otavio Brandao ^{[1
]}

Hoster, Harry E. ^{[1
]}

Gross, Axel ^{[2
]}

Behm, R. Juergen ^{[1
]}

机构：

[1] Univ Ulm, Inst Catalysis & Surface Chem, D-89069 Ulm, Germany

[2] Univ Ulm, Inst Theoret Chem, D-89069 Ulm, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 24期

关键词：

SUPRAMOLECULAR ASSEMBLIES; FORCE-FIELD; SUBSTRATE; LAYERS; ADLAYERS; GRAPHITE; NETWORKS; GROWTH; RANGE;

D O I：

10.1021/ja2025855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The competition between intermolecular interactions and lateral variations in the molecule substrate interactions has been studied by scanning tunneling microscopy (STM), comparing the phase formation of (sub)-monolayers of the organic molecule 2,4'-BTP on buckled graphene/Ru(0001) and Ag(111) oriented thin films on Ru(0001). On the Ag films, the molecules form a densely packed 2D structure, while on graphene/Ru(0001), only the areas between the maxima are populated. The findings are rationalized by a high corrugation in the adsorption potential for 2,4'-BTP molecules on graphene/Ru(0001). These findings are supported by temperature programmed desorption (TPD) experiments and theoretical results.

引用

页码：9208 / 9211

页数：4

共 36 条

[1] The role of intermolecular and molecule-substrate interactions in the stability of alkanethiol nonsaturated phases on Au(111) [J].

Barrena, E ;

Palacios-Lidón, E ;

Munuera, C ;

Torrelles, X ;

Ferrer, S ;

Jonas, U ;

Salmeron, M ;

Ocal, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :385-395

[2]

Bartels L, 2010, NAT CHEM, V2, P87, DOI [10.1038/NCHEM.517, 10.1038/nchem.517]

[3] Molecular architectonic on metal surfaces [J].

Barth, Johannes V. .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2007, 58 :375-407

[4] Engineering atomic and molecular nanostructures at surfaces [J].

Barth, JV ;

Costantini, G ;

Kern, K .

NATURE, 2005, 437 (7059) :671-679

[5] Thermal evolution of a platinum cluster encapsulated in carbon nanotubes [J].

Cheng, Daojian ;

Wang, Wenchuan ;

Huang, Shiping .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (04) :1631-1637

[6] Molecular assembly of rubrene on a metal/metal oxide nanotemplate [J].

Cicoira, Fabio ;

Miwa, Jill A. ;

Perepichka, Dmitrii F. ;

Rosei, Federico .

JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (49) :12674-12678

[7] Balancing Intermolecular and Molecule-Substrate Interactions in Supramolecular Assemblies [J].

de Oteyza, Dimas G. ;

Silanes, Inaki ;

Ruiz-Oses, Miguel ;

Barrena, Esther ;

Doyle, Bryan P. ;

Arnau, Andres ;

Dosch, Helmut ;

Wakayama, Yutaka ;

Enrique Ortega, J. .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (02) :259-264

[8] Structural properties and site specific interactions of Pt with the graphene/Ru(0001) moire overlayer [J].

Donner, Kerstin ;

Jakob, Peter .

JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (16)

[9] Molecular and Supramolecular Networks on Surfaces: From Two-Dimensional Crystal Engineering to Reactivity [J].

Elemans, Johannes A. A. W. ;

Lei, Shengbin ;

De Feyter, Steven .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (40) :7298-7332

[10] Ultrathin organic films grown by organic molecular beam deposition and related techniques [J].

Forrest, SR .

CHEMICAL REVIEWS, 1997, 97 (06) :1793-1896

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