SAFT1 for associating fluids: Alkanols

被引：20

作者：

Adidharma, H ^{[1
]}

Radosz, M ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem & Petr Engn, Laramie, WY 82071 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2001年 / 105卷 / 40期

关键词：

D O I：

10.1021/jp003688a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The SAFT1 equation of state is extended using Wertheim's theory to model associating fluids and tested on pure alkanols and mixtures containing alkanols. For small 1-alkanols, SAFT1 is found to represent the vapor pressure and liquid density. The SAFT1 parameters are shown to be well-behaved and hence possible to estimate for high-molecular-weight 1-alkanols and hydroxy polymers on the basis of their molecular weight alone.

引用

页码：9822 / 9827

页数：6

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