Heating-induced abnormal increase in Yb3+ excited state lifetime and its potential application in lifetime luminescence nanothermometry

被引：46
作者：
Ji, Zeliang [1 ,2 ,3 ]
Cheng, Yao [1 ,2 ]
Cui, Xiangshui [1 ,2 ]
Lin, Hang [1 ,2 ]
Xu, Ju [1 ,2 ]
Wang, Yuansheng [1 ,2 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
[3] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY FRONTIERS | 2019年 / 6卷 / 01期
基金：
中国国家自然科学基金;
关键词：
UP-CONVERSION; FLUORESCENCE; TEMPERATURE; THERMOMETRY; PROBES; NANOPARTICLES; SENSITIVITY;
D O I：
10.1039/c8qi01052h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heating-induced unprecedented monotonous increase in Yb3+ excited state (F-2(5/2)) lifetime is found in Nd3+/Yb3+ codoped fluoride nanoparticles, which is proved to originate from the alleviation of energy migration-mediated surface quenching with elevated temperature. This unique phenomenon is evaluated for thermometric performance in terms of lifetime luminescence thermometry, and the maximum absolute/relative temperature sensitivity (S-a/S-r) reaches as high as 2.68 mu s K-1/1.59% K-1 in the biological temperature region, indicating that the studied nanomaterial can offer great potential for lifetime luminescence thermometry in biological areas.
引用
收藏
页码：110 / 116
页数：7
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