Synthesis and Characterization of Novel Poly (Acrylic Acid/Sodium Alginate/Sodium Humate) Superabsorbent Hydrogels. Part II: The Effect of SH Variation on Cu2+, Pb2+, Fe2+ Metal Ions, MB, CV Dye Adsorption Study

被引:21
作者
Agnihotri, Shipra [1 ]
Singhal, Reena [1 ]
机构
[1] Harcourt Butler Tech Univ, Dept Plast Technol, Kanpur 208002, Uttar Pradesh, India
关键词
Superabsorbent hydrogel (SAHs); Sodium humate (SH); Acrylic acid (AAc); Sodium alginate (NaAlg); Heavy metal ions; Dyes adsorption; AQUEOUS-SOLUTIONS; METHYLENE-BLUE; SWELLING BEHAVIORS; WASTE-WATER; REMOVAL; EQUILIBRIUM; KINETICS; NICKEL(II); SURFACES; CADMIUM;
D O I
10.1007/s10924-017-0956-y
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A novel superabsorbent hydrogel (SAHs) composed of (acrylic acid, sodium alginate and sodium humate) (AAc/NaAlg/SH) SAHs were tested as adsorbent for metal ions Cu2+, Pb2+, and Fe2+ ions as well as MB and CV dyes. The influence of SH concentration varies from 6.97, 8.04, 9.09, 10.11% and 11 wt% were designated as S-1, S-2, S-3, S-4, S-5, respectively. The synthesized superabsorbent hydrogel were used for the adsorption of Cu2+, Pb2+, Fe2+ and MB and CV dyes from their aqueous solutions. The binding capacity for Cu2+, Pb2+, Fe2+ ions were 311 mg/gm/L at 850 mg/L, 209 mg/gm/L at 850 mg/L and 197 mg/gm/L at 850 mg/L for initial ion concentration respectively and MB and CV dyes molecules were 323 mg/gm/L at 360 mg/L, 289 mg/gm/L at 360 mg/L for initial molecule concentration per gram of AAc/NaAlg/SH containing 9.09 wt% SH content. The adsorption data obeyed Langmuir sorption isotherms.
引用
收藏
页码:383 / 395
页数:13
相关论文
共 41 条
[21]   Adsorption of methylene blue on Cu(II)-exchanged montmorillonite [J].
Ma, YL ;
Xu, ZR ;
Guo, T ;
You, P .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 280 (02) :283-288
[22]  
Mahadavinia GR, 2012, J MAT ENV SCI, V3, P895
[23]   kappa-Carrageenan beads as new adsorbent to remove crystal violet dye from water: adsorption kinetics and isotherm [J].
Mahdavinia, Gholam Reza ;
Bazmizeynabad, Fatemeh ;
Seyyedi, Behnam .
DESALINATION AND WATER TREATMENT, 2015, 53 (09) :2529-2539
[24]   Synthesis of CarAlg/MMt nanocomposite hydrogels and adsorption of cationic crystal violet [J].
Mahdavinia, Gholam Reza ;
Aghaie, Huriyeh ;
Sheykhloie, Hossein ;
Vardini, Mohammad Taghi ;
Etemadi, Hossein .
CARBOHYDRATE POLYMERS, 2013, 98 (01) :358-365
[25]  
Mahdavinia GR, 2014, J ENV ENG, V2, P1587
[26]   Facile and green rout to prepare magnetic and chitosan-crosslinked κ-carrageenan bionanocomposites for removal of methylene blue [J].
Mandavinia, Gholam Reza ;
Mosallanezhad, Amirabbas .
JOURNAL OF WATER PROCESS ENGINEERING, 2016, 10 :143-155
[27]   Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study [J].
Milosavljevic, Nedeljko B. ;
Ristic, Mirjana D. ;
Peric-Grujic, Aleksandra A. ;
Filipovic, Jovanka M. ;
Strbac, Svetlana B. ;
Rakocevic, Zlatko Lj. ;
Krusic, Melina T. Kalagasidis .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2011, 388 (1-3) :59-69
[28]   The study of adsorption characteristics Cu2+ and Pb2+ ions onto PHEMA and P(MMA-HEMA) surfaces from aqueous single solution [J].
Moradi, O. ;
Aghaie, M. ;
Zare, K. ;
Monajjemi, M. ;
Aghaie, H. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 170 (2-3) :673-679
[29]  
Murat T., 2008, RADIAT PHYS CHEM, V77, P447
[30]   Removal of Cd(II) from aqueous solutions using clarified sludge [J].
Naiya, T. K. ;
Bhattacharya, A. K. ;
Das, S. K. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 325 (01) :48-56