A one-pot microwave-assisted non-aqueous sol-gel approach to metal oxide/graphene nanocomposites for Li-ion batteries

被引：68

作者：

Baek, Seunghwan ^{[1
]}

Yu, Seung-Ho ^{[1
]}

Park, Seung-Keun ^{[3
]}

Pucci, Andrea ^{[2
]}

Marichy, Catherine ^{[2
]}

Lee, Dong-Chan ^{[1
]}

Sung, Yung-Eun ^{[1
]}

Piao, Yuanzhe ^{[3
]}

Pinna, Nicola ^{[1
,2
]}

机构：

[1] Seoul Natl Univ, Coll Engn, Sch Chem & Biol Engn, Program Chem Convergence Energy & Environm C2E2,W, Seoul 151744, South Korea

[2] Univ Aveiro, CICECO, Dept Chem, P-3810193 Aveiro, Portugal

[3] Seoul Natl Univ, Dept Nano Sci & Technol, Suwon 443270, South Korea

来源：

RSC ADVANCES | 2011年 / 1卷 / 09期

基金：

新加坡国家研究基金会;

关键词：

ANODE MATERIAL; OXIDE NANOPARTICLES; REVERSIBLE CAPACITY; CYCLIC PERFORMANCE; BENZYL ALCOHOL; COMPOSITE; HYBRID; ROUTES; NANOSTRUCTURES; NANOCRYSTALS;

D O I：

10.1039/c1ra00797a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot non-aqueous synthesis of crystalline SnO2- and Fe3O4-based graphene heterostructures in just a few minutes is introduced. The combined properties of the microwave heating and the "benzyl alcohol route" allow the selective growth of metal oxide nanoparticles at the surface of graphene oxide, which is reduced during synthesis. The as-fabricated nanostructures show good lithium intercalation-deintercalation performances at high rate and good cycling stability compared to the separated nano-building blocks.

引用

页码：1687 / 1690

页数：4

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