Ordering phenomena and phase transitions in a spin-crossover compound-uncovering the nature of the intermediate phase of [Fe(2-PiC)3]Cl2•EtOH

被引：249
作者：
Chernyshov, D
Hostettler, M
Törnroos, KW
Bürgi, HB
机构：
[1] Univ Bern, Lab Kristallog, CH-3012 Bern, Switzerland
[2] Univ Bergen, Dept Chem, Bergen, Norway
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 32期
关键词：
iron; low-temperature crystallography; N ligands; order-disorder phase transition; spin crossover;
D O I：
10.1002/anie.200351834
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From disorder to order and back: Contrary to all earlier studies on [Fe(2-pic)3]Cl2· EtOH (pic = picolylamine), an ordered phase (IP) with two crystallographically different iron sites was found between disordered high-spin (HS) and low-spin (LS) phases. The picture shows the average Fe-N distances of all three phases.
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收藏
页码：3825 / 3830
页数：6
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