Preparation and characterization of titanium tungstophosphate immobilized on mesoporous silica SBA-15 as a new inorganic composite ion exchanger for the removal of lanthanum from aqueous solution

被引:8
作者
Ahmadi, M. [1 ]
Yavari, R. [2 ]
Faal, A. Y. [1 ]
Aghayan, H. [2 ]
机构
[1] Payame Noor Univ, Dept Chem, POB 37185-311, Qom, Iran
[2] NFCS, NSTRI, POB 11365-8486, Tehran, Iran
关键词
Inorganic composite; Mesoporous silica (SBA-15); Titanium tungstophosphate; Adsorption; Lanthanum ions; TRIBLOCK COPOLYMER; DIBLOCK COPOLYMER; ADSORPTION; ACID; EXTRACTION; SEPARATION; SURFACTANT; BENTONITE; SORPTION; CARBONS;
D O I
10.1007/s10967-016-4748-y
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study, a novel inorganic composite ion exchanger based on titanium tungstophosphate (TWP) and mesoporous silica SBA-15 has been synthesized. The synthesized product was characterized by methods and instrumental techniques. The results obtained from X-ray diffraction, N-2 adsorption-desorption and Fourier transform infrared analysis confirm immobilization of TWP on SBA-15. Consequently, the ability of this composite for the adsorption of lanthanum ions from aqueous solution was investigated. Considering the relatively high adsorption capacity of lanthanum onto synthesized composite, this material can be potential candidate for the removal of even trace amount of lanthanum ions from nuclear and other industrial wastewater.
引用
收藏
页码:177 / 190
页数:14
相关论文
共 49 条
[1]   Studies on extraction and separation of La(III) with DEHPA and PC88A in petrofin [J].
Acharya, Sagarika ;
Mishra, Sujata ;
Misra, P. K. .
HYDROMETALLURGY, 2015, 156 :12-16
[2]   Samarium and dysprosium removal using 11-molybdo-vanadophosphoric acid supported on Zr modified mesoporous silica SBA-15 [J].
Aghayan, H. ;
Mahjoub, A. R. ;
Khanchi, A. R. .
CHEMICAL ENGINEERING JOURNAL, 2013, 225 :509-519
[3]   Synthesis and characterization of cesium molybdo vanado phosphate immobilized on platelet SBA-15: An efficient inorganic composite ion-exchanger for gadolinium ion sorption [J].
Aghayan, H. ;
Khanchi, A. R. ;
Mahjoub, A. R. .
APPLIED SURFACE SCIENCE, 2013, 274 :7-14
[4]   Amine-modified polyacrylamide-bentonite composite for the adsorption of humic acid in aqueous solutions [J].
Anirudhan, T. S. ;
Suchithra, P. S. ;
Rijith, S. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 326 (03) :147-156
[5]  
[Anonymous], 1963, J. Sanit. Eng. Div. Am. Soc. Civ. Eng, DOI DOI 10.1061/JSEDAI.0000430
[6]   Preparation, characterization and analytical application of stannic molybdophosphate immobilized on multiwalled carbon nanotubes as a new adsorbent for the removal of strontium from wastewater [J].
Asadollahi, N. ;
Yavari, R. ;
Ghanadzadeh, H. .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2015, 303 (03) :2445-2455
[7]   Application of amine-functionalized MCM-41 modified ultrafiltration membrane to remove chromium (VI) and copper (II) [J].
Bao, Yixiang ;
Yan, Xiaomin ;
Du, Wei ;
Xie, Xiaoni ;
Pan, Zhaoqi ;
Zhou, Jialu ;
Li, Laisheng .
CHEMICAL ENGINEERING JOURNAL, 2015, 281 :460-467
[8]  
Biswajit Das, 2013, CHEM SCI T, V2, P85, DOI [DOI 10.1016/J.JHAZMAT.2007.06.067, DOI 10.7598/CST2013.318]
[9]   Catalytic performance of vanadium-substituted molybdophosphoric acid supported on zirconium modified mesoporous silica in oxidative desulfurization [J].
Chamack, M. ;
Mahjoub, A. R. ;
Aghayan, H. .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2015, 94 :565-572
[10]   A facile route to synthesizing functionalized mesoporous SBA-15 materials with platelet morphology and short mesochannels [J].
Chen, Shih-Yuan ;
Tang, Chih-Yuan ;
Chuang, Wei-Tsung ;
Lee, Jey-Jau ;
Tsai, Yi-Ling ;
Chan, Jerry C. C. ;
Lin, Ching-Yen ;
Liu, Yu-Cheng ;
Cheng, Soofin .
CHEMISTRY OF MATERIALS, 2008, 20 (12) :3906-3916